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In a mass spectrum, peaks labeled as nonrepeating have been found to occur only once, that is, not at periodically spaced m/z intervals of 162.07 Da, the mass of AcOSty monomer. Consequently, these peaks are unlikely to correspond to poly(AcOSty) material but rather are deemed to be impurities existing within the sample. These peaks typically disappear upon repeating the mass spectrometric analysis. 56. The normalized experimental noise was estimated by hand-picking the apex of a representative peak in a region that contained only a background signal and comparing this abundance value with that of ideal stars
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In a mass spectrum, peaks labeled as nonrepeating have been found to occur only once, that is, not at periodically spaced m/z intervals of 162.07 Da, the mass of AcOSty monomer. Consequently, these peaks are unlikely to correspond to poly(AcOSty) material but rather are deemed to be impurities existing within the sample. These peaks typically disappear upon repeating the mass spectrometric analysis. 56. The normalized experimental noise was estimated by hand-picking the apex of a representative "peak" in a region that contained only a background signal and comparing this abundance value with that of ideal stars.
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