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Volumn 37, Issue 7, 2004, Pages 2404-2410

Facile Access to Chain Length Dependent Termination Rate Coefficients via Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization: Influence of the RAFT Agent Structure

Author keywords

[No Author keywords available]

Indexed keywords

APPROXIMATION THEORY; COMPUTER SIMULATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MOLECULAR STRUCTURE; MONTE CARLO METHODS; REACTION KINETICS;

EID: 6344280414     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0358428     Document Type: Article
Times cited : (54)

References (50)
  • 8
    • 0035781101 scopus 로고    scopus 로고
    • Fischer, H. Chem. Rev. 2001, 101, 3581-3610.
    • (2001) Chem. Rev. , vol.101 , pp. 3581-3610
    • Fischer, H.1
  • 9
    • 16544393204 scopus 로고    scopus 로고
    • note
    • The statement that the radical concentration is unaltered in RAFT systems is strictly speaking only true for chain length independent termination kinetics. However, a nonretarding RAFT system comes very close to the situation of an unchanged radical population compared to the corresponding conventional polymerization. An identical approximation is true for the rate of polymerization. Nevertheless, it must be stated that the use of the calculated radical concentration (from the conventional system) constitutes an assumption.
  • 47
    • 16544366089 scopus 로고    scopus 로고
    • note
    • i,i.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.