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Device 2 was fabricated using step iii but with a 30%/70% volume ratio of DAN/Br-Pr-Br. 1,2-Dibromoethane was used to form device 3 by mixing 1.5 mM solutions of these in a 50%/50% volume ratio with DAN and immediately spin-casting on the surface (step iii replacing Cl-Pr-SH). Device 3 was fabricated by spin coating a 5 mM solution of DAN in ethanol on the substrate without support of organic film followed by drying at T = 80 °C for half an hour. Device containing diluted concentration of DAN in DAN/Cl-Pr-SH system, which did not form crystalline phase and device 3 do not exhibit features of field effect or FN devices. Corresponding surface chemistry was performed to obtain structures 1-3 on glass for spectroscopic, XRD and XPS studies.
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Device 2 was fabricated using step iii but with a 30%/70% volume ratio of DAN/Br-Pr-Br. 1,2-Dibromoethane was used to form device 3 by mixing 1.5 mM solutions of these in a 50%/50% volume ratio with DAN and immediately spin-casting on the surface (step iii replacing Cl-Pr-SH). Device 3 was fabricated by spin coating a 5 mM solution of DAN in ethanol on the substrate without support of organic film followed by drying at T = 80 °C for half an hour. Device containing diluted concentration of DAN in DAN/Cl-Pr-SH system, which did not form crystalline phase and device 3 do not exhibit features of field effect or FN devices. Corresponding surface chemistry was performed to obtain structures 1-3 on glass for spectroscopic, XRD and XPS studies.
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