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Volumn 10, Issue 8, 2008, Pages 1125-1132

Pronounced non-Arrhenius behaviour of hydrogen-abstractions from toluene and derivatives by phthalimide-N-oxyl radicals: A theoretical study

Author keywords

[No Author keywords available]

Indexed keywords

BENZALDEHYDE; BENZALDEHYDE DERIVATIVE; BENZYL ALCOHOL; DRUG DERIVATIVE; HYDROGEN; ISOTOPE; PHTHALIMIDE; PHTHALIMIDE DERIVATIVE; REACTIVE OXYGEN METABOLITE; TOLUENE;

EID: 39049127470     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/b716932a     Document Type: Article
Times cited : (31)

References (39)
  • 38
    • 11144306080 scopus 로고    scopus 로고
    • Cambridge University Press, This value takes into account counter rotation of the phenyl group to conserve the angular momentum
    • W. Forst, in Unimolecular Reactions, Cambridge University Press, 2003
    • (2003) Unimolecular Reactions
    • Forst In, W.1
  • 39
    • 23044439796 scopus 로고    scopus 로고
    • It was assumed in ref. 15 that every alkyl radical (Ṙ) produced would react with a second PINȮ radical, putting the stoichiometric coefficient for PINȮ at 2: every primary PINȮ + RH reaction step would result in net removal of two PINȮ radicals. It can not be excluded that other secondary reactions would also occur to some extent, such as the reverse reaction of Ṙ with NHPI, regenerating PINȮ radicals, causing an underestimation of the actual rate constant
    • C. Canepa M. Mosso A. Maranzana G. Tonachini Eur. J. Org. Chem. 2005 3342
    • (2005) Eur. J. Org. Chem. , vol.3342
    • Canepa, C.1    Mosso, M.2    Maranzana, A.3    Tonachini, G.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.