The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents

Journal of Fluorine Chemistry

Volumn 129, Issue 3, 2008, Pages 167-172

  Dostál, Libor ^a   Jambor, Roman ^a   Růžička, Aleš ^a   Jirásko, Robert ^a   Císařová, Ivana ^b   Holeček, Jaroslav ^a  

^a UNIVERSITY OF PARDUBICE   (Czech Republic)

^b CHARLES UNIVERSITY   (Czech Republic)

Author keywords

Antimony; Chelating ligand; Fluorine; Tin; X ray structure

Indexed keywords

EID: 38949217744     PISSN: 00221139     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jfluchem.2007.10.003     Document Type: Article

References (36)

1. Jagirdar B.R., Murphy E.F., and Roesky H.W. In: Karlin K.D. (Ed). Progress in Inorganic Chemistry vol. 48 (1999), John Wiley and Sons 351-455 and references cited therein
2. Roesky H.W. Inorg. Chem. 38 (1999) 5934-5943
3. Murphy E.F., Murugavel R., and Roesky H.W. Chem. Rev. 97 (1997) 3425-3468
4. Singh S., and Roesky H.W. J. Fluorine Chem. 128 (2007) 369-377
5. Ohkata K., Ohnishi M., and Akiba K. Tetrahedron Lett. 29 (1988) 5401-5404
6. Gibbons M.N., Begley M.J., Blake A.J., and Sowerby D.B. J. Chem. Soc. Dalton Trans. (1997) 2419-2425
7. Kojima S., Takagi R., Nakata H., Yamamoto Y., and Akiba K. Chem. Lett. (1995) 857-858
8. Rahman A.F.M.M., Murafuji T., Ishibashi M., Miyoshi Y., and Sugihara Y. J. Organomet. Chem. 689 (2004) 3395-3401
9. Yamamoto Y., Kojima S., Fujishima H., Fujikawa H., and Akiba K. Bull. Soc. Chim. Belg. 106 (1997) 651-657
10. Matano Y., Begum S.A., Miyamatsu T., and Suzuki H. Organometallics 18 (1999) 5668-5681
11. Minoura M., Kanamori Y., Miyake A., and Akiba K. Chem. Lett. (1999) 861-862
12. Rahman A.F.M.M., Murafuji T., Kurotobi K., and Sugihara Y. Organometallics 23 (2004) 6176-6183
13. Yamaguchi S., Shirasaka T., and Tamao K. Organometallics 21 (2002) 2555-2558
14. Matano Y., Begum S.A., and Suzuki H. Synthesis (2001) 1081-1085
15. Ohkata K., Takemoto S., Ohnishi M., and Akiba K. Tetrahedron Lett. 30 (1989) 4841-4844
16. Bone S.P., and Sowerby D.B. J. Chem. Soc., Dalton (1979) 1430-1433
17. Baiget L., Bouslikhane M., Escudie J., Nemes G.C., Silaghi-Dumitrescu I., and Silaghi-Dumitrescu L. Phosphorus, Sulfur Silicon 178 (2003) 1949-1961
18. Shimada S., Yamazaki O., Tanaka T., Suzuki Y., and Tanaka M. J. Organomet. Chem. 689 (2004) 3012-3023
19. Suzuki H., Murafuji T., and Azuma N. J. Chem. Soc. Perkin Trans. 1 (1993) 1169-1175
20. Suzuki H., Murafuji T., Matano Y., and Azuma N. J. Chem. Soc. Perkin Trans. 1 (1993) 2969-2973
21. Soran A.P., Silvestru C., Breunig H.J., Balász G., and Green J.C. Organometallics 26 (2007) 1196-1203
22. Dostál L., Císařová I., Jambor R., Růžička A., Jirásko R., and Holeček J. Organometallics 25 (2006) 4366-4373
23. Atwood D.A., Cowley A.H., and Ruiz J. Inorg. Chim. Acta 198-200 (1992) 271-274
24. Herzog A., Lin F.Q., Roesky H.W., Demsar A., Keller K., Noltemeyer M., and Pauer F. Organometallics 13 (1994) 1251-1256
25. Bareš J., Novák P., Nádvorník M., Jambor R., Lébl T., Císařová I., Růžička A., and Holeček J. Organometallics 23 (2004) 2967-2971
26. Novák P., Brus J., Císařová I., Růžička A., and Holeček J. J. Fluorine Chem. 126 (2005) 1531-1538
27. Novák P., Padělková Z., Císařová I., Kolářová L., Růžička A., and Holeček J. Appl. Organomet. Chem. 20 (2006) 226-232
28. Švec P., Novák P., Nádvorník M., Padělková Z., Císařová I., Růžička A., and Holeček J. J. Fluorine Chem. 128 (2007) 1390-1395
29. 119Sn NMR) the isolation of pure 6 was even more difficult.
30. Handwerker H., Leis C., Probst R., Bassinger P., Grohmann A., Kiprof P., Herdtweek F., Blümel J., Auner N., and Zybill C. Organometallics 12 (1993) 2162-2176
31. Spek A.L. PLATON, A Multipurpose Crystallographic Tool (2005), Utrecht University, Utrecht, The Netherlands. http://www.cryst.chem.uu.nl/platon/ available at
32. Kojima S., Doi Y., Okuda M., and Akiba K. Organometallics 14 (1995) 1928-1937
33. This structure can be also described as a ψ-octahedron, if the lone pair of central metal is included in the overall geometry. This lone pair is then located in trans position to C1. The last possible description is bicapped-trigonal pyramid, where Sb1, C1, F1 and F2 form trigonal pyramid that is cis coordinated by two donor atoms. (O for 4 and 5 and N for 6).
34. Coppens P. Acta Cryst. A 26 (1970) 71-83
35. Altomare A., Cascarano G., Giacovazzo C., Guagliardi A., Burla M.C., Polidori G., and Camalli M. J. Appl. Cryst. 27 (1994) 435-1435
36. G.M. Sheldrick, SHELXL97 University of Göttingen, Germany (1997).