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Volumn 23, Issue 26, 2004, Pages 6176-6183

First introduction of an azulenyl group into the bismuth and antimony center. Synthesis and structure of azulenylbismuthanes and their difluorides

Author keywords

[No Author keywords available]

Indexed keywords

ANTIMONY; BISMUTH COMPOUNDS; COORDINATION REACTIONS; ELECTRONIC STRUCTURE; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; POLARIZATION; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

EID: 11044235791     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om040053f     Document Type: Article
Times cited : (17)

References (28)
  • 13
    • 0034608836 scopus 로고    scopus 로고
    • The coordination number-photophysical property relationships for the tri(9-anthryl)derivatives of boron, silicon, phosphorus, and bismuth, see: (a) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6335. (b) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2001, 123, 11372. (c) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6793. (d) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Organomet. Chem. 2002, 646, 277. (e) Yamaguchi, S.; Shirasaka, T.; Tamao, K. Organometallics 2002, 21, 2555.
    • (2000) J. Am. Chem. Soc. , vol.122 , pp. 6335
    • Yamaguchi, S.1    Akiyama, S.2    Tamao, K.3
  • 14
    • 0035930009 scopus 로고    scopus 로고
    • The coordination number-photophysical property relationships for the tri(9-anthryl)derivatives of boron, silicon, phosphorus, and bismuth, see: (a) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6335. (b) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2001, 123, 11372. (c) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6793. (d) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Organomet. Chem. 2002, 646, 277. (e) Yamaguchi, S.; Shirasaka, T.; Tamao, K. Organometallics 2002, 21, 2555.
    • (2001) Chem. Soc. , vol.123 , pp. 11372
    • Yamaguchi, S.1    Akiyama, S.2    Am, T.K.J.3
  • 15
    • 0034686727 scopus 로고    scopus 로고
    • The coordination number-photophysical property relationships for the tri(9-anthryl)derivatives of boron, silicon, phosphorus, and bismuth, see: (a) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6335. (b) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2001, 123, 11372. (c) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6793. (d) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Organomet. Chem. 2002, 646, 277. (e) Yamaguchi, S.; Shirasaka, T.; Tamao, K. Organometallics 2002, 21, 2555.
    • (2000) J. Am. Chem. Soc. , vol.122 , pp. 6793
    • Yamaguchi, S.1    Akiyama, S.2    Tamao, K.3
  • 16
    • 0036499664 scopus 로고    scopus 로고
    • The coordination number-photophysical property relationships for the tri(9-anthryl)derivatives of boron, silicon, phosphorus, and bismuth, see: (a) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6335. (b) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2001, 123, 11372. (c) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6793. (d) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Organomet. Chem. 2002, 646, 277. (e) Yamaguchi, S.; Shirasaka, T.; Tamao, K. Organometallics 2002, 21, 2555.
    • (2002) J. Organomet. Chem. , vol.646 , pp. 277
    • Yamaguchi, S.1    Akiyama, S.2    Tamao, K.3
  • 17
    • 0038682381 scopus 로고    scopus 로고
    • The coordination number-photophysical property relationships for the tri(9-anthryl)derivatives of boron, silicon, phosphorus, and bismuth, see: (a) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6335. (b) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2001, 123, 11372. (c) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6793. (d) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Organomet. Chem. 2002, 646, 277. (e) Yamaguchi, S.; Shirasaka, T.; Tamao, K. Organometallics 2002, 21, 2555.
    • (2002) Organometallics , vol.21 , pp. 2555
    • Yamaguchi, S.1    Shirasaka, T.2    Tamao, K.3
  • 18
    • 0000534859 scopus 로고
    • π-Polarization is observed in diaryltrifluorosilicates. Thus, the ipso carbons attached to the pentacoordinate silicon appear more downfield compared to those of the parent tetracoordinate silanes. This is attributed to the π-inductive effect induced by the electronic fields of the charged substituents. The upfield shift of the ipso carbons in the pentacoordinate antimony and bismuth halides may be ascribed to this π-inductive effect. For the π-polarization of the silicates, see: Tamao, K.; Hayashi, T.; Ito, Y. Organometallics 1992, 11, 182.
    • (1992) Organometallics , vol.11 , pp. 182
    • Tamao, K.1    Hayashi, T.2    Ito, Y.3


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