Synthesis, structures, and UV-visible absorption spectra of tri(9 anthryl)bismuthine derivatives

Organometallics

Volumn 21, Issue 12, 2002, Pages 2555-2558

  Yamaguchi, Shigehiro ^a,b   Shirasaka, Toshiaki ^a   Tamao, Kohei ^a  

^a KYOTO UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; BISMUTH COMPOUNDS; CRYSTAL STRUCTURE; DERIVATIVES; SYNTHESIS (CHEMICAL); ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

PACKING STRUCTURES;

ORGANOMETALLICS;

EID: 0038682381     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020124f     Document Type: Article

References (25)

1. A mini-review: Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Organomet. Chem., in press.
2. (a) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6335.
3. (b) Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2001, 123, 11372.
4. Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Am. Chem. Soc. 2000, 122, 6793.
5. Yamaguchi, S.; Akiyama, S.; Tamao, K. J. Organomet. Chem. 2002, 646, 277.
6. Properties control based on the changes in the valence states of the main group elements: (a) Barbarella, G.; Favaretto, L.; Zambianchi, M.; Pudova, O.; Arbizzani, C.; Bongini, A.; Mastragostino, M.-Adv. Mater. 1998, 10, 551.
7. (b) Barbarella, G.; Favaretto, L.; Sotgiu, G.; Zambianchi, M.; Bongini, A.; Arbizzani, C.; Mastragostino, M.; Anni, M.; Gigli, G.; Cingolani, R. J. Am. Chem. Soc. 2000, 122, 11971.
8. (c) Barbarella, G.; Favaretto, L.; Sotgiu, G.; Zambianchi, M.; Antolini, L.; Marseglia, E. A.; Tedesco, E.; Gigli, G.; Cingolani, R. Synth. Met. 2000, 115, 47.
9. (d) Jiang B.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9744.
10. (e) Suh, M. C.; Jiang, B.; Tilley, T. D. Angew. Chem., Int. Ed. 2000, 39, 2870.
11. (f) Hay, C.; Vilain, D. L.; Deborde, V.; Toupet, L.; Réau, R. Chem. Commun. 1999, 345.
12. (g) Hay, C.; Fischmeister, C.; Hissler, M.; Toupet, L.; Réau, R. Angew. Chem., Int. Ed. 2000, 39, 2870.
13. (h) Hay, C.: Hissler, M.; Fischmeister, C.; Rault-Berthelot, J.; Toupet, L.; Nyulaszi, L.; Reau, R. Chem. Eur. J. 2001, 7, 4222.
14. Through this paper, the discussion is made from a viewpoint of the changes in the coordination number rather than the changes in the valence state in order to compare the present results to the previous silicon case.
15. For example, 3b completely decomposed into 9-butylanthracene, 10,10′-dibutyl-9,9′-bianthryl, and other unidentified compounds upon standing in a benzene solution under an oxygen atmosphere for 6 h under ambient light. The photoreactivity of triarylbismuthines, see: (a) Matano, Y.; Ikegami, T. Organobismuth Chemistry; Matano, Y., Suzuki, H., Eds.; Elsevier Science: Amsterdam, 2001; pp 21-246.
16. (b) Alberti, A.; Hudson, A. J. Organomet. Chem. 1979, 182, C49.
17. Ogawa, T. Organobismuth Chemistry; Matano, Y., Suzuki, H. Eds.; Elsevier Science: Amsterdam, 2001; pp 441-546.
18. UV-visible absorption spectra of triarylbismuthines: (a) Rao, C. N. R.; Ramachandran, J.; Balasubramanian, A. Can, J. Chem. 1961, 39, 171.
19. (b) Zohn, H.; Sohindlbauer, H.; Hammer, D. Monatsh. Chem. 1967, 98, 731.
20. (c) Matano, Y.; Kurata, H.; Murafuji, T.; Azuma, N.; Suzuki, H. Organometallics 1998, 17, 4049.
21. Although we have attempted to evaluate the fluorescence properties, the present trianthrylbismuth compounds gradually decomposed under the fluorescence measurement condition.
22. Rahman, M. M.; Matano, Y.; Suzuki, H. Organometallics 1997, 16, 3565.
23. 0-0 of 4b relative to that of 4c is attributed to the electronic effect of the butyl groups.
24. Altomore, A.; Burla, M. C.; Camalli, M.; Cascarano, M. Giacovazzo, C.; Guagliardi, A.; Polidori, G. J. Appl. Crystallogr. 1994, 27, 435.
25. Beurskens, P. T.; Admiraal, G.; Beurskens, G.; Bosman, W. P.; Garcia-Granda, S.; Gould, R. O.; Smits, J. M. M.; Smykalla, C. The DIRDIF program system; Techincal Report of the Crystallography Laboratory; University of Nijimegen: The Netherlands, 1992.