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38
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38949182244
-
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60 due to their low polarity.
-
60 due to their low polarity.
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39
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38949090989
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Spectral data for product 2e: 1H NMR (300 MHz, CS2-CDCl3) δ 8.67 (d, J, 8.8 Hz, 2H, δ 8.62 (d, J, 8.8 Hz, 2H, 6.67 (s, 1H, 13C NMR (75 MHz, CS2-CDCl3 with Cr(acac)3 as relaxation agent all 2C unless indicated) δ 153.54 (1C, aryl C, 150.85, 150.63, 146.68 (1C, 146.58 (1C, 146.30 (1C, 145.57, 145.47 (4C, 145.29 (4C, 144.78, 144.68, 144.61, 144.50, 144.42, 144.33, 143.68, 143.43, 142.35, 141.70 (4C, 141.20, 141.06 (4C, 140.76, 140.71 (4C, 139.57, 139.28, 135.12, 135.02, 127.85 (aryl C, 124.29 (aryl C, 66.53 (1C, sp3-C of C60, 62.52 (1C2 sp3-C of C60, FT-IR (KBr) υ max (cm-1) 2922,2852, 1603, 1516, 1427, 1345, 1185, 1111, 853, 731, 583, 527; MS (MALDI-TOF) m/z 842 (M-1, UV-vis CHCl3, λmax nm log ε
-
max nm (log ε) 256 (5.16), 309 (4.71), 431 (3.64), 698 (2.70).
-
-
-
-
40
-
-
38949213300
-
-
2).
-
2).
-
-
-
-
41
-
-
38949213986
-
-
Spectral data for product 4: 1H NMR (300 MHz, CS2-CDCl3) δ 7.47 (d, J, 8.7 Hz, 2H, 6.88 (d, J, 8.7 Hz, 2H, 3.80 (s, 3H, OCH3, 13C NMR (75 MHz, CS2-CDCl3 with Cr(acac)3 as relaxation agent all 2C unless indicated) δ 154.52 (1C, aryl C, 146.51, 143.55, 143.50, 143.40, 143.18, 143.13, 143.06 (3C, 143.02, 142.82 (3C, 142.55, 142.33 (4C, 142.16 (4C, 142.11, 141.92, 141.89 141.76, 141.68, 140.61, 140.20 (3C, 139.23 (1C, 139.64, 139.52, 137.55, 136.77 (1C, aryl C, 136.65, 136.27, 135.75, 133.87, 116.52 (aryl C, 113.63 (aryl C, 54.57 (1C, OCH3, FT-IR (KBr) υmax (cm-1) 2922, 2826, 1556, 1506, 1460, 1437, 1395, 1344, 1285, 1243, 1179, 1036, 821, 619, 525; MS (MALDI-TOF) m/z 841 (M, UV-vis (CHCl3) λmax nm (log ε) 260 (5.20, 329 (4.57, 502 (3.42, 544 3.36
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max nm (log ε) 260 (5.20), 329 (4.57), 502 (3.42), 544 (3.36).
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