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23
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38949217888
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2: yield: 8.3mg (56, Anal. Found (calcd for C20H 13Cl3N2OSn, C, 46.04(45.98, H, 2.67(2.51, N, 5.26(5.36, 3: yield: 7.1mg (46, Anal. Found (calcd for C 20H13Cl3N2O3Sn, C, 47.03(47.02, H, 2.86(2.82, N, 5.21(5.22, 4: yield: 8.3 mg (64, Anal. Found (calcd for C20H19Cl3N2OSn, C, 42.32(42.86, H, 3.20(3.42, N, 5.08(5.00, 5: yield: 54.8 mg (73, Anal. Found (calcd for C16H10Cl3N 3O3Sn, C, 37.02(37.15, H, 1.78(1.95, N, 7.988.12
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3Sn): C, 37.02(37.15); H, 1.78(1.95); N, 7.98(8.12)%.
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38949190140
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Crystallographic data have been deposited with Cambridge Crystallographic Data Centre as supplementary: No. 656122, 1; 656123, 3; 661505, 5; 656124, HL2
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Crystallographic data have been deposited with Cambridge Crystallographic Data Centre as supplementary: No. 656122, 1; 656123, 3; 661505, 5; 656124, HL2.
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25
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C. Pérez-Bolivar, V. A. Montes, P. Anzenbacher, Jr., Inorg. Chem. 2006, 45, 9610.
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Pérez-Bolivar, C.1
Montes, V.A.2
Anzenbacher Jr., P.3
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26
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38949097660
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One electron reduction processes were observed in DMSO, and the reduction processes are irreversible. Oxidation of the complexes caused decomposition
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One electron reduction processes were observed in DMSO, and the reduction processes are irreversible. Oxidation of the complexes caused decomposition.
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0000872324
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F. E. Lytle, D. R. Storey, M. E. Juricich, Spectrochim. Acta, Part A 1973, 29, 1357.
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Lytle, F.E.1
Storey, D.R.2
Juricich, M.E.3
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28
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38949143183
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HL4′, which turns to L4 on coordination to tin(IV), is fluorescent. HL5 is unstable in DMSO.
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HL4′, which turns to L4 on coordination to tin(IV), is fluorescent. HL5 is unstable in DMSO.
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29
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38949176916
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The main components of HOMOs of 1-5 are the aldehyde moieties of the ligands and those of LUMOs are the quinoline moieties, therefore the electronic configuration of the emitting states can be assigned to charge transfer within the ligands.
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The main components of HOMOs of 1-5 are the aldehyde moieties of the ligands and those of LUMOs are the quinoline moieties, therefore the electronic configuration of the emitting states can be assigned to charge transfer within the ligands.
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38949118853
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Presented at the 57th Symp. on Coordination Chemistry of Japan, Nagoya, September 25-27, 2007, Abstr., No. 1Fa-15.
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Presented at the 57th Symp. on Coordination Chemistry of Japan, Nagoya, September 25-27, 2007, Abstr., No. 1Fa-15.
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38949142500
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Supporting Information is available electronically on the CSJ-Journal web site
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Supporting Information is available electronically on the CSJ-Journal web site, http://www.csj.jp/journals/chem-lett/.
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