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Volumn 130, Issue 4, 2008, Pages 1431-1439

Does the solid-liquid crystal phase transition provoke the spin-state change in spin-crossover metallomesogens?

Author keywords

[No Author keywords available]

Indexed keywords

METALLOMESOGENS; PSEUDO-OCTAHEDRAL SYMMETRY; SPIN-CROSSOVER (SCO);

EID: 38849133000     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja077265z     Document Type: Article
Times cited : (111)

References (49)
  • 1
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    • Spin Crossover in Transition Metal Compounds
    • Gütlich, P, Goodwin, H. A, Eds, Springer: Berlin, 234
    • (a) Gütlich, P., Goodwin, H. A., Eds. Spin Crossover in Transition Metal Compounds. Topics in Current Chemistry; Springer: Berlin, 2004; Vol. 233, 234, 235.
    • (2004) Topics in Current Chemistry , vol.233 , pp. 235
  • 11
    • 28544443382 scopus 로고    scopus 로고
    • (e) Binnemans, K. Chem. Rev. 2005, 11, 4148-4204.
    • (2005) Chem. Rev , vol.11 , pp. 4148-4204
    • Binnemans, K.1
  • 14
    • 0004256575 scopus 로고    scopus 로고
    • VCH: Weinheim, Germany, and references therein
    • (a) Serrano, J. L. Metallomesogens; VCH: Weinheim, Germany, 1996 and references therein,
    • (1996) Metallomesogens
    • Serrano, J.L.1
  • 18
    • 0037903256 scopus 로고    scopus 로고
    • Gimenez, R.; Lydon.-D. P.; Serrano, J. L. Curr. Opin. Solid State Mater. Sci. 2002, 6, 527-535.
    • (e) Gimenez, R.; Lydon.-D. P.; Serrano, J. L. Curr. Opin. Solid State Mater. Sci. 2002, 6, 527-535.
  • 32
    • 0348080703 scopus 로고    scopus 로고
    • (b) Irie, M. Chem. Rev. 2000, 100, 1685.
    • (2000) Chem. Rev , vol.100 , pp. 1685
    • Irie, M.1
  • 43
  • 44
    • 38849173315 scopus 로고    scopus 로고
    • CrysAlis CCD, version 1.171.29; Oxford Diffraction Ltd: Poland, 2006; Wrocław
    • CrysAlis CCD, version 1.171.29; Oxford Diffraction Ltd: Poland, 2006; Wrocław.
  • 45
    • 38849203824 scopus 로고    scopus 로고
    • CrysAlis RED, version 1.171.29; Oxford Diffraction Ltd: Poland, 2006; Wrocław
    • CrysAlis RED, version 1.171.29; Oxford Diffraction Ltd: Poland, 2006; Wrocław.
  • 46
    • 0004150157 scopus 로고    scopus 로고
    • University of Göttingen: Göttingen, Germany
    • Sheldrick, G. M. SHELXS97/SHELXL97; University of Göttingen: Göttingen, Germany, 1997.
    • (1997) SHELXS97/SHELXL97
    • Sheldrick, G.M.1
  • 47
    • 38849199448 scopus 로고    scopus 로고
    • MT increases following the spin-transition curve observed for each compound.
    • MT increases following the spin-transition curve observed for each compound.
  • 48
    • 38849159566 scopus 로고    scopus 로고
    • MT with increasing temperature below the maximum conversion is due to die well-known zero-field splitting effect.
    • MT with increasing temperature below the maximum conversion is due to die well-known zero-field splitting effect.
  • 49
    • 38849124463 scopus 로고    scopus 로고
    • The hydrated samples were placed in open containers in the SQUID sample holder and their magnetism measured. The first part of the experiment comprised several cycles of heating-cooling from 280 until 350 K (empty squares, Then, the samples were left for 2 h at the reported temperatures (indicated by arrows) and the magnetic moment was measured (open circles, Dehydration taking place under these conditions is confirmed by the thermogravimetric analysis SFigure 1
    • The hydrated samples were placed in open containers in the SQUID sample holder and their magnetism measured. The first part of the experiment comprised several cycles of heating-cooling from 280 until 350 K (empty squares). Then, the samples were left for 2 h at the reported temperatures (indicated by arrows) and the magnetic moment was measured (open circles). Dehydration taking place under these conditions is confirmed by the thermogravimetric analysis (SFigure 1).


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