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y (x = 1, y = 4; x = 2, y = 3).
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38749146667
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2. It was found that while complex 2 was formed, two other uncharacterized products were also produced.
-
2. It was found that while complex 2 was formed, two other uncharacterized products were also produced.
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27
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38749112727
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Signals for complex 2 can also been seen upon thermolysis of Ru(PPh3)2(CO)3 in the presence of excess I iPr2Me2 at 333 K, showing that the cis-NHC arrangement is not simply a kinetic phenomenon. However, the reaction is slow and leads to a number of other unidentifiable products being formed see ref 19
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2 at 333 K, showing that the cis-NHC arrangement is not simply a kinetic phenomenon. However, the reaction is slow and leads to a number of other unidentifiable products being formed (see ref 19).
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38749148628
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3 methyl resonance broadened (down to ca. 240 K) before sharpening again at 216 K.
-
3 methyl resonance broadened (down to ca. 240 K) before sharpening again at 216 K.
-
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35
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38749091895
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Warming toluene samples of 2 and 3 above 323 K resulted in gradual decomposition of the samples see ref 15, preventing high-temperature NMR data from being recorded
-
Warming toluene samples of 2 and 3 above 323 K resulted in gradual decomposition of the samples (see ref 15), preventing high-temperature NMR data from being recorded.
-
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36
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38749114811
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See the Supporting Information for VT NMR spectra of 1-3 in other solvents
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See the Supporting Information for VT NMR spectra of 1-3 in other solvents.
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37
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37049116061
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For other reports describing the oxidation of Ru/Os mono- and dicarbonyl complexes, see: (a) Laing, K. R.; Roper, W. R. J. Chem. Soc., Chem. Commun. 1968, 1568-1569.
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41
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38749092773
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This was the only solvent that allowed dissolution of both the starting tricarbonyl complexes (which reacted with CD2Cl2) and carbonato products which showed limited solubility in THF
-
2) and carbonato products (which showed limited solubility in THF).
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42
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0006061730
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0001054345
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3 has been shown to be very slow in the solid state and to fail altogether in solution. Valentine, J.; Valentine, D., Jr.; Collman, J. P Inorg. Chem. 1971, 10, 219-225.
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47
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38749095678
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See also ref 21d
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Sheldrick, G. M. Acta Crystallogr. 1990, 467-473, A46. Sheldrick, G. M, SHELXL-97, a computer program for crystal structure refinement, University of Göttingen, 1997.
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