-
5
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38349066344
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note
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Representative examples of tertiary carbinol containing bioactive compounds: Cinatrin C, Integerrimine, Harringtonine, K-252-a, Fostriecin, Viridofungin, Erythromycin and Zaragozic acid.
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-
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6
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0001403071
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Asymmertic epoxidation:. Jacobsen E.N., Pfaltz A., and Yamamoto H. (Eds), Springer, Heidelberg Chapter 18.1
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Asymmertic epoxidation:. Katsuki T. In: Jacobsen E.N., Pfaltz A., and Yamamoto H. (Eds). Comprehensive Asymmetric Catalysis Vol. 2 (1999), Springer, Heidelberg Chapter 18.1
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(1999)
Comprehensive Asymmetric Catalysis
, vol.2
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Katsuki, T.1
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7
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0000345527
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Jacobsen E.N., Pfaltz A., and Yamamoto H. (Eds), Springer, Heidelberg Chapter 18.2
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Jacobsen E.N., and Wu M.F. In: Jacobsen E.N., Pfaltz A., and Yamamoto H. (Eds). Comprehensive Asymmetric Catalysis Vol. 2 (1999), Springer, Heidelberg Chapter 18.2
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(1999)
Comprehensive Asymmetric Catalysis
, vol.2
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Jacobsen, E.N.1
Wu, M.F.2
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9
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0003445429
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Asymmetric hydroxylation:. Jacobsen E.N., Pfaltz A., and Yamamoto H. (Eds), Springer, Heidelberg Chapter 20
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Asymmetric hydroxylation:. Marko I.E., and Svensen J.S. In: Jacobsen E.N., Pfaltz A., and Yamamoto H. (Eds). Comprehensive Asymmetric Catalysis Vol. 2 (1999), Springer, Heidelberg Chapter 20
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(1999)
Comprehensive Asymmetric Catalysis
, vol.2
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Marko, I.E.1
Svensen, J.S.2
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18
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0042681991
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and references cited therein
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Chen F., Feng X., Qin B., Zhang G., and Jiang Y. Org. Lett. 5 (2003) 949 and references cited therein
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(2003)
Org. Lett.
, vol.5
, pp. 949
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-
Chen, F.1
Feng, X.2
Qin, B.3
Zhang, G.4
Jiang, Y.5
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20
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33745711830
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Chen C., Hong L., Xu Z.-Q., Zhao-Qing V., Liu L., and Wang R. Org. Lett. 8 (2006) 2277
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(2006)
Org. Lett.
, vol.8
, pp. 2277
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Chen, C.1
Hong, L.2
Xu, Z.-Q.3
Zhao-Qing, V.4
Liu, L.5
Wang, R.6
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29
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0037999777
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For the application of this methodology in the synthesis of bioactive target molecules refer:
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For the application of this methodology in the synthesis of bioactive target molecules refer:. Raghavan S., and Ramakrishna Reddy S. J. Org. Chem. 68 (2003) 5754
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(2003)
J. Org. Chem.
, vol.68
, pp. 5754
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-
Raghavan, S.1
Ramakrishna Reddy, S.2
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41
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0034719257
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The unsaturated aldehydes were obtained from the corresponding esters in two steps, (a) reduction using DIBAL-H to furnish the allyl alcohols followed by (b) oxidation using Swern protocol. The esters themselves were prepared using procedures reported in the literature, ester corresponding to 2, refer:
-
The unsaturated aldehydes were obtained from the corresponding esters in two steps, (a) reduction using DIBAL-H to furnish the allyl alcohols followed by (b) oxidation using Swern protocol. The esters themselves were prepared using procedures reported in the literature, ester corresponding to 2, refer:. Koppisch A.T., Blagg B.S.J., and Poulter C.D. Org. Lett. 2 (2000) 215
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(2000)
Org. Lett.
, vol.2
, pp. 215
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Koppisch, A.T.1
Blagg, B.S.J.2
Poulter, C.D.3
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42
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0344961695
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For ester corresponding to 3 refer:
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For ester corresponding to 3 refer:. Baldwin I.R., and Whitby R.J. Chem. Commun. (2003) 2786
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(2003)
Chem. Commun.
, pp. 2786
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-
Baldwin, I.R.1
Whitby, R.J.2
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43
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0028792481
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For ester corresponding to 4 refer:
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For ester corresponding to 4 refer:. Nicolaou K.C., Liu J.-J., Yang Z., Ueno H., Sorensen E.J., Claiborne C.F., Guy R.K., Hwang C.-K., Nakada M., and Nantermet P.G. J. Am. Chem. Soc. 117 (1995) 634
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(1995)
J. Am. Chem. Soc.
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, pp. 634
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-
Nicolaou, K.C.1
Liu, J.-J.2
Yang, Z.3
Ueno, H.4
Sorensen, E.J.5
Claiborne, C.F.6
Guy, R.K.7
Hwang, C.-K.8
Nakada, M.9
Nantermet, P.G.10
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45
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0001296747
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The configuration of anti- and syn-isomers were assigned by comparison of coupling constants for the methylene protons directly bonded to the carbon of the β-hydroxy sulfoxide moiety and the chemical shift of the β-methine proton. Refer: and references cited therein
-
The configuration of anti- and syn-isomers were assigned by comparison of coupling constants for the methylene protons directly bonded to the carbon of the β-hydroxy sulfoxide moiety and the chemical shift of the β-methine proton. Refer:. Carreno M.C., Garcia Ruano T.L., Martin A.M., Pedregal C., Rodrigues J.H., Rubio A., Sanchez J., and Solladie G. J. Org. Chem. 55 (1990) 2120 and references cited therein
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J. Org. Chem.
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, pp. 2120
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Carreno, M.C.1
Garcia Ruano, T.L.2
Martin, A.M.3
Pedregal, C.4
Rodrigues, J.H.5
Rubio, A.6
Sanchez, J.7
Solladie, G.8
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47
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0040454662
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For a modern interpretation, see:
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For a modern interpretation, see:. Isenberg N., and Grdinic M. J. Chem. Educ. 46 (1969) 601
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(1969)
J. Chem. Educ.
, vol.46
, pp. 601
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Isenberg, N.1
Grdinic, M.2
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49
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38349071003
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See Electronic Supplementary data.
-
-
-
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50
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0037047517
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18O and X-ray crystallography, refer:
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18O and X-ray crystallography, refer:. Raghavan S., Ramakrishna Reddy S., Tony K.A., Naveen Kumar Ch., Varma A.K., and Nangia A. J. Org. Chem. 67 (2002) 5838
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J. Org. Chem.
, vol.67
, pp. 5838
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-
Raghavan, S.1
Ramakrishna Reddy, S.2
Tony, K.A.3
Naveen Kumar, Ch.4
Varma, A.K.5
Nangia, A.6
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51
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0347600407
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Raghavan S., Rajender A., Joseph S.C., Rasheed M.A., and Ravikumar K. Tetrahedron: Asymmetry 15 (2004) 365
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(2004)
Tetrahedron: Asymmetry
, vol.15
, pp. 365
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Raghavan, S.1
Rajender, A.2
Joseph, S.C.3
Rasheed, M.A.4
Ravikumar, K.5
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52
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4444276560
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Raghavan S., Naveen Kumar Ch., Tony K.A., Ramakrishna Reddy S., and Ravikumar K. Tetrahedron Lett. 45 (2004) 7231
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(2004)
Tetrahedron Lett.
, vol.45
, pp. 7231
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Raghavan, S.1
Naveen Kumar, Ch.2
Tony, K.A.3
Ramakrishna Reddy, S.4
Ravikumar, K.5
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53
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0001071070
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Ref. 7l. Also refer: The positive optical rotation for the substrates and the negative rotation for the products also support inversion of sulfoxide configuration, refer: Electronic Supplementary data
-
Ref. 7l. Also refer:. Dalton D.R., Dutta V.P., and Jones D.C. J. Am. Chem. Soc. 90 (1968) 5498 The positive optical rotation for the substrates and the negative rotation for the products also support inversion of sulfoxide configuration, refer: Electronic Supplementary data
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(1968)
J. Am. Chem. Soc.
, vol.90
, pp. 5498
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Dalton, D.R.1
Dutta, V.P.2
Jones, D.C.3
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56
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0001296747
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Carreno M.C., Garcia Ruano J.L., Martin A., Pedregal C., Rodrigues J.H., Rubio A., Sanchez J., and Solladie G. J. Org. Chem. 55 (1990) 2120
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(1990)
J. Org. Chem.
, vol.55
, pp. 2120
-
-
Carreno, M.C.1
Garcia Ruano, J.L.2
Martin, A.3
Pedregal, C.4
Rodrigues, J.H.5
Rubio, A.6
Sanchez, J.7
Solladie, G.8
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70
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0037035352
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Miyashita K., Ikejiri M., Kawasaki H., Maemura S., and Imanishi T. Chem. Commun. (2002) 742
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Chem. Commun.
, pp. 742
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Miyashita, K.1
Ikejiri, M.2
Kawasaki, H.3
Maemura, S.4
Imanishi, T.5
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72
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0038682505
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Miyashita K., Ikejiri M., Kawasaki H., Maemura S., and Imanishi T. J. Am. Chem. Soc. 125 (2003) 8238
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Miyashita, K.1
Ikejiri, M.2
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Maemura, S.4
Imanishi, T.5
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15744395371
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Trost B.M., Frederiksen M.U., Papillon J.P.N., Harrington P.E., Shin S., and Shireman B.T. J. Am. Chem. Soc. 127 (2005) 3666
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Trost, B.M.1
Frederiksen, M.U.2
Papillon, J.P.N.3
Harrington, P.E.4
Shin, S.5
Shireman, B.T.6
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79
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38349072068
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note
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Compound 15 was obtained from 7s prepared in two steps (i. formation of β-keto sulfoxide and ii. stereoselective reduction of keto sulfoxide, 53% overall yield) as depicted {A figure is presented}.
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