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The alcohol is too hindered to allow easy introduction of the TBS ether.
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0442317931
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note
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-1), and the p-methoxybenzylidene acetal formed by oxidative cyclization with DDQ, which showed the expected NOE between 1,3 diaxial protons.
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29
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0442286494
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note
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-1).
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32
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0442270881
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note
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-1, indicative of a five-membered carbonate.
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