Determining transition state structure using kinetic isotope effects

Journal of Labelled Compounds and Radiopharmaceuticals

Volumn 50, Issue 11-12, 2007, Pages 989-1005

  Westaway, Kenneth C ^a  

^a LAURENTIAN UNIVERSITY   (Canada)

Author keywords

Nucleophilic substitution; Primary nucleophile KIEs; Primary carbon KIEs; Primary leaving group KIEs; SN2; Secondary alpha deuterium KIEs; Secondary beta deuterium KIEs; Transition state structure

Indexed keywords

CARBON; DEUTERIUM;

DEUTERIUM KINETIC ISOTOPE EFFECT; KINETIC ISOTOPES EFFECTS; LEAVING GROUPS; NUCLEOPHILIC SUBSTITUTIONS; PRIMARY NUCLEOPHILE KINETIC ISOTOPE EFFECT; PRIMARY Α; PRIMARY Α-CARBON KINETIC ISOTOPE EFFECT; PRIMARY-LEAVING GROUP KINETIC ISOTOPE EFFECT; SECONDARY ALPHA; SECONDARY ALPHA DEUTERIUM KINETIC ISOTOPE EFFECT; SECONDARY BETA DEUTERIUM KINETIC ISOTOPE EFFECT; TRANSITION STATE STRUCTURE; Α-CARBON KINETIC ISOTOPE EFFECTS;

NUCLEOPHILES;

CARBON; DEUTERIUM; ISOTOPE;

IONIC STRENGTH; ISOTOPE LABELING; KINETICS; ORGANIC CHEMISTRY; REVIEW; TEMPERATURE DEPENDENCE;

EID: 38349011466     PISSN: 03624803     EISSN: 10991344     Source Type: Journal    
DOI: 10.1002/jlcr.1434     Document Type: Review

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