Solvent effects on nucleophilic substitution reactions. III. The effect of adding an inert salt on the structure of the SN2 transition state

Canadian Journal of Chemistry

Volumn 74, Issue 12, 1996, Pages 2528-2530

  Pham, T V ^a   Westaway, K C ^a  

^a LAURENTIAN UNIVERSITY   (Canada)

Author keywords

Ionic strength; Nitrogen isotope effects; SN2; Secondary deuterium kinetic isotope effects; Transition state

Indexed keywords

ADDITION REACTIONS; AMMONIUM COMPOUNDS; DEUTERIUM; ELECTRON TRANSITIONS; ELECTRONIC DENSITY OF STATES; IONIC STRENGTH; IONS; ORGANIC SOLVENTS; REACTION KINETICS; SALTS;

BENZYLDIMETHYLPHENYLAMMONIUM ION; INERT SALT; TRIOPHENOXIDE ION;

SUBSTITUTION REACTIONS;

EID: 0030380132     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v96-283     Document Type: Article

References (13)

1. E.S. Gould. In Mechanism and structure in organic chemistry. Holt, Reinhart, and Winston, Inc., New York. 1959. 185.
2. K.C. Westaway and S.F. Ali. Can. J. Chem. 57, 1354 (1979).
3. W.H. Saunders. Chem. Scr. 8, 27 (1975).
4. S. Wolfe and C.-K. Kim. J. Am. Chem. Soc. 113, 8056 (1991).
5. R.A. Poirier, Y. Wang, and K.C. Westaway. J. Am. Chem. Soc. 116, 2526 (1994).
6. J.A. Barnes and I.H. Williams. J. Chem. Soc. Chem. Commun. 1286 (1993).
7. T.R. Griffin, D.B. Cook, A. Haynes, J.M. Pearson, D. Monti, and G.E. Morris. J. Am. Chem. Soc. 118, 3029 (1996).
8. S. Hoz, S. Basch, and M.J. Goldberg. J. Am. Chem. Soc. 114, 4364 (1992).
9. D. Stefanidis and W.P. Jencks. J. Am. Chem. Soc. 115, 6045 (1993).
10. I. Lee, W.H. Lee, and H.W. Lee. J. Phys. Org. Chem. 3, 545 (1990).
11. K.C. Westaway and Z. Waszczylo. Can. J. Chem. 60, 2500 (1982).
12. T.V. Pham, Y.R. Fang, and K.C. Westaway. J. Am. Chem. Soc. In press.
13. T.V. Pham. M.Sc. Dissertation, Laurentian University, 1993.