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Volumn , Issue 35, 2007, Pages 5926-5933

Synthesis and rearrangement of 1,2,3-triheteroaryl(aryl)-substituted aziridines

Author keywords

Aziridines; Carbanions; Enamines; Nitrogen heterocycles; Rearrangement

Indexed keywords


EID: 37349107461     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.200700462     Document Type: Article
Times cited : (11)

References (45)
  • 1
    • 33748605775 scopus 로고
    • For reviews on aziridines, see: a
    • For reviews on aziridines, see: a) D. Tanner, Angew. Chem. Int. Ed. Engl. 1994, 33, 599-619;
    • (1994) Angew. Chem. Int. Ed. Engl , vol.33 , pp. 599-619
    • Tanner, D.1
  • 4
    • 0003216627 scopus 로고
    • Eds, B. M. Trost, I. Fleming, Pergamon, Oxford
    • a) J. Aube, Comprehensive Organic Synthesis (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, vol. 2, p. 428;
    • (1991) Comprehensive Organic Synthesis , vol.2 , pp. 428
    • Aube, J.1
  • 5
    • 0001318042 scopus 로고    scopus 로고
    • b) T. Satoh, Chem. Rev. 1996, 96, 3303-3325;
    • (1996) Chem. Rev , vol.96 , pp. 3303-3325
    • Satoh, T.1
  • 7
    • 1542375289 scopus 로고    scopus 로고
    • X. E. Hu, Tetrahedron 2004, 60, 2701-2743.
    • (2004) Tetrahedron , vol.60 , pp. 2701-2743
    • Hu, X.E.1
  • 12
    • 85071411058 scopus 로고    scopus 로고
    • A. Dondoni in Modern Synthetic Methods (Ed.: R. Sheffold), Helvetica Chimica Acta, Basel, 1992, pp. 377-473.
    • A. Dondoni in Modern Synthetic Methods (Ed.: R. Sheffold), Helvetica Chimica Acta, Basel, 1992, pp. 377-473.
  • 34
    • 85071406627 scopus 로고    scopus 로고
    • X-ray crystallographic data for 21a: C20H 15N3S, T, 123 K, 0.22 × 0.16 × 0.13 mm3, yellow, prismatic crystal, triclinic, space group P1, a, 11.155(2) Å, b, 11.671(2) Å, c, 13.575(2) Å, α, 82.32(2)°, β, 74.05(2)°, γ, 75.25(2)°, V, 1639.4(5) Å3, Z, 4, Dcalcd, 1.335 g cm-3, λ (Mo-K α, 0.71073 Å, μ (Mo-Kα, 0.203 mm-1. Data collection: Bruker SMART APEX diffractometer, Oxford low temperature device, data collection blow 2θ, 55°, 16357 data collected, 7519 independent, 4549 observed [I > 2σ(I, The structure was solved by SIR2002 M. C. Burla, M. Camalli, B. Carrozzini, G. L. Cascarano, C. Giacovazzo, G. Polidori, R. Spagna, J. Appl. Cryst. 2003
    • -1. Data collection: Bruker SMART APEX diffractometer, Oxford low temperature device, data collection blow 2θ = 55°, 16357 data collected, 7519 independent, 4549 observed [I > 2σ(I)]. The structure was solved by SIR2002 (M. C. Burla, M. Camalli, B. Carrozzini, G. L. Cascarano, C. Giacovazzo, G. Polidori, R. Spagna, J. Appl. Cryst. 2003, 36, 1103),
  • 35
    • 85071409911 scopus 로고    scopus 로고
    • and refined on F2 by SHELX97 (G. M. Sheldrick, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997, Final R, 0.0484, wR, 0.0867, on observed data, goodness-of-fit, 0.950, 0.29 < Δp < 0.24 e Å-3. The crystal structure of 21a contains two independent molecules; their conformations are similar, in spite of some geometrical parameters differing significantly. In particular, the intramolecular distance N18⋯N13 (hydrogen bonded) is 2.804(2) Å and 2.741(2) Å in the two independent molecules. Other quite significant differences are, for example, the torsion angles S1-C2-C10-N18 and C2-C10-N18-C19, whose values are 37.5(2, 23.4(2) and 47.9(3, 57.1(3)°, respectively, for the two independent molecules. CCDC-638681 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge
    • -3. The crystal structure of 21a contains two independent molecules; their conformations are similar, in spite of some geometrical parameters differing significantly. In particular, the intramolecular distance N18⋯N13 (hydrogen bonded) is 2.804(2) Å and 2.741(2) Å in the two independent molecules. Other quite significant differences are, for example, the torsion angles S1-C2-C10-N18 and C2-C10-N18-C19, whose values are 37.5(2), 23.4(2) and 47.9(3), 57.1(3)°, respectively, for the two independent molecules. CCDC-638681 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
  • 41
    • 85071405762 scopus 로고    scopus 로고
    • Chem. Abstr. 1955, 49, 13223;
    • Chem. Abstr. 1955, 49, 13223;


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.