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Volumn 26, Issue 24, 2007, Pages 5791-5798

Donor-stabilized silyl cations. 12.1 electrochemical evidence for ionic dissociation of hexacoordinate silicon complexes

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROCHEMISTRY; IONIC CONDUCTIVITY; METAL COMPLEXES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POSITIVE IONS; SILANES;

EID: 36749063479     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om700687s     Document Type: Article
Times cited : (7)

References (90)
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    • 2 is that the electrophilic Si in dichelates 1-4 has a large affinity for Cl; hence ion - solvent interactions cannot be neglected.
    • 2 is that the electrophilic Si in dichelates 1-4 has a large affinity for Cl; hence ion - solvent interactions cannot be neglected.
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    • The equilibrium in parentheses may or may not intervene depending on the coordination at silicon
    • The equilibrium in parentheses may or may not intervene depending on the coordination at silicon.
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    • Higher values of ΔS° for close ion pairs compared to ΔS° of solvent-separated pairs (Table 3) also agree with solvent-driven association of these dichelates.
    • Higher values of ΔS° for close ion pairs compared to ΔS° of solvent-separated pairs (Table 3) also agree with solvent-driven association of these dichelates.
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    • Taking no account of the difference in the diffusion coefficients of dichelate 1 and ferrocene
    • Taking no account of the difference in the diffusion coefficients of dichelate 1 and ferrocene.


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