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Volumn 18, Issue 22, 2007, Pages 2613-2616

An investigation into the diastereoselective palladation of oxazoline appended cobalt metallocenes

Author keywords

[No Author keywords available]

Indexed keywords

COBALT DERIVATIVE; OXAZOLINE DERIVATIVE;

EID: 36448980210     PISSN: 09574166     EISSN: 1362511X     Source Type: Journal    
DOI: 10.1016/j.tetasy.2007.10.028     Document Type: Article
Times cited : (15)

References (29)
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    • 2/40-60 petroleum ether prior to use.
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    • 1H NMR spectroscopy.
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    • note
    • pR)-1.
  • 18
    • 36448990181 scopus 로고    scopus 로고
    • note
    • The relative configuration of 1 was originally assigned by an NOE experiment (Ref. 2), and has been confirmed by X-ray crystallography (Ref. 5d).
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    • 36448936503 scopus 로고    scopus 로고
    • note
    • 3, 652.2256.
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    • The palladation of benzene derivatives proceeds via the intermediacy of a cationic Pd(II)-arenium species:
    • The palladation of benzene derivatives proceeds via the intermediacy of a cationic Pd(II)-arenium species:. Canty A.J., and van Koten G. Acc. Chem. Res. 28 (1995) 406-413
    • (1995) Acc. Chem. Res. , vol.28 , pp. 406-413
    • Canty, A.J.1    van Koten, G.2
  • 25
    • 0001104014 scopus 로고    scopus 로고
    • Electrophilic aromatic substitution of ferrocene proceeds with exo attack for acylation and endo attack for mercuration:
    • Electrophilic aromatic substitution of ferrocene proceeds with exo attack for acylation and endo attack for mercuration:. Mayor-López M.J., Weber J., Mannfors B., and Cunningham A.F. Organometallics 17 (1998) 4983-4991
    • (1998) Organometallics , vol.17 , pp. 4983-4991
    • Mayor-López, M.J.1    Weber, J.2    Mannfors, B.3    Cunningham, A.F.4
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    • note
    • 4-tetraphenylcyclobutadiene moiety reducing the likelihood of endo attack.
  • 29
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    • note
    • The minimal energy conformation with respect to the N(1)-C(α) bond is that with the hydrogen attached to the stereogenic centre pointing to the metallocene. Although not specifically studied in solution, this is observed by X-ray crystallography in the solid state, see Ref. 4.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.