Remarkable two-step, four-electron oxidative addition reactions at phosphorus [P(I)-P(V)] in terminal electrophilic phosphinidene complexes

Canadian Journal of Chemistry

Volumn 85, Issue 10, 2007, Pages 885-888

  Graham, Todd W ^a,b   Udachin, Konstantin A ^a,b   Zgierski, Marek Z ^a,b   Carty, Arthur J ^a,b  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^b UNIVERSITY OF OTTAWA   (Canada)

Author keywords

Electrophilic phosphinidene; Low coordinate phosphorus; Oxidative addition; P(I) ligand; Rhenium

Indexed keywords

ADDITION REACTIONS; CHEMICAL REACTIVITY; COMPLEXATION; DENSITY FUNCTIONAL THEORY; LIGANDS; RHENIUM;

ELECTROPHILIC PHOSPHINIDENE; LOW COORDINATE PHOSPHORUS; OXIDATIVE ADDITION; PHOSPHORUS LIGANDS;

PHOSPHORUS COMPOUNDS;

EID: 36148959712     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/V07-119     Document Type: Article

References (31)

1. (a) B.T Sterenberg and A. J. Carty. J. Organomet. Chem. 617, 696 (2001);
2. (b) B.T. Sterenberg, K.A. Udachin, and A.J. Carty. Organometallics, 20, 2657 (2001).
3. T.W. Graham, R.P.-Y. Cariou, J. Sánchez-Nieves, A.E. Allen, K.A. Udachin, and A.J. Carty. Organometallics, 24, 2023 (2005).
4. (a) B.T. Sterenberg, K.A. Udachin, and A.J. Carty. Organometallics, 22, 3927 (2003);
5. (b) T.W. Graham, K.A. Udachin, and A.J. Carty. Chem. Commun. 5890 (2005).
6. J. Sánchez-Nieves, B.T. Sterenberg, K.A. Udachin, and A.J. Carty. J. Am. Chem. Soc. 125, 2404 (2003).
7. R. Waterman and G.L. Hillhouse. Organometallics, 22, 5182 (2003).
8. (a) F. Mathey. Angew. Chem., Int. Ed. Engl. 26, 275 (1987);
9. (b) F. Mathey, N.H. Tran Huy, and A. Marinetti. Helv. Chim. Acta, 84, 2938 (2001);
10. (c) K. Lammertsma. Top. Curr. Chem. 229, 95 (2003).
11. (a) G. Zhao, F. Basuli, U.J. Kilgore, H. Fan, H. Aneetha, J.C. Huffman, G. Wu, G., and D.J. Mindiola. J. Am. Chem. Soc. 128, 13575 (2006);
12. (b) R. Waterman and G.L. Hillhouse. J. Am. Chem. Soc. 125, 13350 (2003);
13. (c) A.T. Termaten, H. Aktas, M. Schäkel, A.W. Ehlers, M. Lutz, A.L. Spek, and K. Lammertsma. Organometallics, 22, 1827 (2003);
14. (d) R. Melenkivitz, D.J. Mindiola, and G.L. Hillhouse. J. Am. Chem. Soc. 124, 3846 (2002);
15. (e) Z. Hou, T.L. Breen, and D.W. Stephan. Organometallics, 12, 3158 (1993);
16. (f) C.C. Cummins, R.R. Schrock, and W.M. Davis. Angew. Chem., Int. Ed. Engl. 32, 756 (1993).
17. B.T. Sterenberg, K.A. Udachin, and A.J. Carty. Organometallics, 20, 4463 (2001).
18. A.J. Termaten, T. Nijbacker, M. Schäkel, M. Lutz, A.L. Spek, and K. Lammertsma. Organometallics, 21, 3196 (2002).
19. J.P. Collman, L.S. Hegedus, J.R. Norton, and R.G. Finke. Principies and applications of organotransition metal chemistry. University Science Books, Mill Valley, California. 1987. Vol. 1. pp. 279-353.
20. B.T. Sterenberg, J. Sánchez-Nieves, and A.J. Carty. Unpublished results.
21. P.W. Codding and K.A. Kerr. Acta. Crystallogr., Sect. B: Struct. Sci. 34, 3785 (1978).
22. H.R. Hayes and D.J. Peterson. In Organic phosphorus compounds. Edited by G.M. Kosolapoff and L. Maier. Wiley-Interscience, New York. 1972. Vol. 3. p. 341.
23. Density functional calculations were performed with the GAUSSIAN 98 program package with the BP 86: (a) A.D. Becke. Phys. Rev. A, 38, 3098 (1988);
24. (b) J.P. Perdew. Phys. Rev. B. 33, 8822 (1986);
25. set of functionals and cc-pVDZ basis set for all first, second, and third row atoms. For Re, relativistic pseudopotentials for core electrons and a LANL2DZ ECP basis set for all other electrons were used.
26. T.W. Graham, J. Kickham, S. Courtenay, P. Wei, and D.W. Stephan. Organometallics, 23, 3309 (2004).
27. (a) T.W. Graham, K.A. Udachin, and A.J. Carty. Inorg. Chim. Acta, 360, 1376 (2007);
28. (b) T.W. Graham, K.A. Udachin, and A. J. Carty. Chem. Commun. 35, 4441 (2005).
29. (a) N. Burford, T.S. Cameron, K.D. Conroy, B.D. Ellis, M. Lumsden, C.L.B. MacDonald, R. McDonald, A.D. Phillips, P.J. Ragogna, R.W. Schurko, D. Walsh, and R.E. Wasylishen. J. Am. Chem. Soc. 124, 14012 (2002);
30. (b) B.D. Ellis, C.A. Dyker, A. Decken, and C.L.B. MacDonald. Chem. Commun. 15, 1965 (2005).
31. R.B. King and N.D. Sadanani. Synth. React. Inorg. Met.-Org. Chem. 15, 149 (1985).