Exploring conversion of biphasic catalytic reactions: Analytical solution and parameter study

Industrial and Engineering Chemistry Research

Volumn 46, Issue 22, 2007, Pages 7073-7078

  Peters, Martina ^a   Eckstein, Marrit F ^a   Hartjen, Gert ^a   Spiess, Antje C ^a   Leitner, Walter ^a   Greiner, Lasse ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

INDUSTRIAL APPLICATIONS; PARAMETER ESTIMATION; SUBSTRATES;

BIPHASIC CATALYTIC REACTIONS; REACTION EFFICIENCY; SUBSTRATE RATIO;

CATALYST ACTIVITY;

CATALYST ACTIVITY; INDUSTRIAL APPLICATIONS; PARAMETER ESTIMATION; SUBSTRATES;

EID: 35948996111     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie070402g     Document Type: Article

References (22)

1. Cornils, B.; Herrmann, W. A.; Horvath, I. T.; Leitner, W.; Mecking, S.; Olivier-Bourbigou, H.; Vogt, D. (Hrsg.) Multiphase Homogeneous Catalysis; Wiley-VCH: Weinheim, Germany, 2005.
2. Keim, W. Multiphase catalysis and its potential in catalytic processes: The story of biphasic homogeneous catalysis. Green Chem. 2003, 5, 105-111.
3. Keim, W. Nickel: An Element with Wide Application in Industrial Homogenous Catalysis. Angew. Chem., Int. Ed. Engl. 1990, 29, 235.
4. Kohlpaintner, C. W.; Fischer, R. W.; Cornils, B. Aqueous Biphasic Catalysis: Ruhrchemie/Rhône-Poulenc Oxo Process. Appl Catal., A. 2001, 227, 219-225.
5. Sheldon, R. A. Green solvents for sustainable organic synthesis: State of the art. Green Chem. 2005, 7, 267.
6. Ansorge-Schumacher, M. B.; Greiner, L.; Schroeper, F.; Mirtschin, S.; Hischer, T. Operational concept for the improved synthesis of (R)-3,3'furoin and related hydrophobic compounds with benzaldehyde lyase. Biotechnol. J. 2006, 1, 564.
7. Cull, S. G.; Holbrey, J. D.; Vargas-Mora, V.; Seddon, K. R.; Lye, G. J. Room-temperature ionic liquids as replacements for organic solvents in multiphase bioprocess operations. Biotechnol. Bioeng. 2000, 69, 227.
8. Reetz, M. T.; Wiesenhöfer, W.; Franciò, G.; Leitner, W. Continuous flow enzymatic kinetic resolution and enantiomer separation using ionic liquid/supercritical carbon dioxide media. Adv. Synth. Catal. 2003, 345, 1221.
9. Faber, K. Biotransformations in Organic Chemistry. A Textbook; Springer: Berlin, 2004.
10. Faber, K. Industrial Biotransformations; Springer: Wiley-VCH, Weinheim, Germany, 2006.
11. Carrea, G. Biocatalysis in water-organic solvent two phase systems. Trends Biotechnol. 1984, 2, 102-106.
12. Hailing, P. J. Thermodynamic predictions for biocatalysis in nonconventional media: Theory, tests, and recommendations for experimental design and analysis. Enzyme Microb. Technol 1994, 16, 178-206.
13. Ulijn, R. V.; Halling, P. J. Solid-to-solid biocatalysis: Thermodynamic feasibility and energy efficiency. Green Chem. 2004, 6, 488-496.
14. Uma, R.; Crévisy, G.; Grée, R. Transposition of allylic alcohols into carbonyl compounds mediated by transition metal complexes. Chem. Rev. 2003, 105, 27-51.
15. Klibanov, A. M.; Samokhin, G. P.; Martinek, K.; Berezin, I. V. A new approach to preparative enzymic engineering. Biotechnol. Bioeng. 1977, 19, 1351-1361.
16. Antczak, T.; Hiler, D.; Krystynowicz, A.; Bielecki, S.; Galas, E. Mathematical modelling of ester synthesis by lipase in biphasic system. J. Mol Catal. B: Enzym. 2001, 11, 1043-1050.
17. Martinek, K.; Semenov, A. N.; Berezin, I. V. Enzymatic synthesis in bipasic aqueous-organic systems. I. Chemical equilibrium shin. Biochim. Biophys. Acta 1981, 658, 76-89.
18. Martinek, K.; Semenov, A. N. Enzymatic synthesis in bipasic aqueous-organic systems. II. Shift of ionic equilibrium. Biochim. Biophys. Acta 1981, 655, 90-101.
19. Greiner, L.; Laue, S.; Liese, A.; Wandrey, C. Continuous homogeneos asymmetric transfer hydrogenation of ketones: Lessons from kinetics. Chemistry 2006, 12, 1818-1823.
20. Eckstein, M. F.; Peters, M.; Lembrecht, J.; Spiess, A. C.; Greiner. L. Maximise Equilibrium Conversion in Biphas'ic Catalysed Reactions: Mathematical Description and Practical Guideline. Adv. Synth. Catal. 2006, 348, 1591-1596.
21. Eckstein, M. F.; Lembrecht, J.; Schumacher, J.; Peters, M.; Roosen, C.; Greiner, L.; Eberhard, W.; Spiess, A.; Leitner, W.; Kragl, U. Maximize your equilibrium conversion in biphasic catalysed reactions: How to obtain equilibrium constants for reactions of practical relevance? Adv. Synth. Catal. 2006, 345, 1597-1604.
22. Wisman, R. V.; de Vries, J. G.; Deelman, B. J.; Heeres, H. J. Kinetic studies on the asymmetric transfer hydrogénation of acetophenone using a homogeneous ruthenium catalyst with a chiral amino-alcohol ligand. Org. Process Res. Dev. 2006,10, 423-429.