메뉴 건너뛰기




Volumn 46, Issue 21, 2007, Pages 8457-8459

Solvent-free aerobic oxidation of n-alkane by iron(III)-substituted polyoxotungstates immobilized on SBA-15

Author keywords

[No Author keywords available]

Indexed keywords


EID: 35648977101     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic701178a     Document Type: Article
Times cited : (65)

References (50)
  • 2
    • 0003678023 scopus 로고
    • Oxidations in Organic Chemistry
    • ACS Monograph, American Chemical Society: Washington, DC
    • (b) Hudlucky, M. Oxidations in Organic Chemistry; ACS Monograph Series; American Chemical Society: Washington, DC, 1990.
    • (1990) Series
    • Hudlucky, M.1
  • 17
    • 0011820784 scopus 로고    scopus 로고
    • Hill, C. L, Ed, American Chemical Society: Washington, DC
    • (b) Chemical Reviews, Polyoxometalates; Hill, C. L., Ed.; American Chemical Society: Washington, DC, 1998.
    • (1998) Chemical Reviews, Polyoxometalates
  • 21
    • 3442886712 scopus 로고    scopus 로고
    • Borrás-Almenar, J. J, Coronado, E, Müller, A, Pope, M. T, Eds, Kluwer: Dordrecht, The Netherlands
    • (f) Polyoxometalate Molecular Science; Borrás-Almenar, J. J., Coronado, E., Müller, A., Pope, M. T., Eds.; Kluwer: Dordrecht, The Netherlands, 2004.
    • (2004) Polyoxometalate Molecular Science
  • 42
    • 35648932115 scopus 로고    scopus 로고
    • Briefly, 1 g of mesoporous silica SBA-15 was heated to 130°C for 5 h in vacuum to remove the adsorbed water. Then, under a nitrogen atmosphere, 30 mL of a 1 wt, solution of apts in anhydrous toluene was added to the silica. After refluxing for 5 h, the solids were filtered and washed with toluene to remove unanchored apts. The solids were collected and dried for the condensation process to obtain the amino group modified silica. To immobilize Fe 4X2W18 thereon, 0.5 g of the modified silica was mixed with 100 mL of water, and HCl (2 M) was added to adjust the pH to about 2. Then, 0.1 g of a POM was added, and the mixture was stirred for 8 h. The solids were filtered and washed with water and then dried. The same modification and immobilization procedure was appliedjo SiO2 and MCM-41. The final loadings were determined by elemental analysis
    • 2 and MCM-41. The final loadings were determined by elemental analysis.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.