Stereodivergent synthesis of chiral 2-alkenylaziridines: Palladium(0)-catalyzed 2,3-cis-selective aziridination and base-mediated 2,3-trans-selective aziridination

Chemical and Pharmaceutical Bulletin

Volumn 52, Issue 1, 2004, Pages 111-119

  Ohno, Hiroaki ^a   Takemoto, Yoshiji ^b   Fujii, Nobutaka ^b   Tanaka, Tetsuaki ^a   Ibukab, Toshiro ^b  

^a OSAKA UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

Aziridine; Cyclization; Palladium; Stereodivergent synthesis; Stereoselectivity

Indexed keywords

1,4 DIOXANE DERIVATIVE; ALCOHOL DERIVATIVE; ALLYL COMPOUND; AZIRIDINE DERIVATIVE; CARBONIC ACID; CIS ACTING ELEMENT; MESYLIC ACID DERIVATIVE; PALLADIUM; SODIUM DERIVATIVE; TRANS ACTING FACTOR; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS;

ARTICLE; AZIRIDINATION; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS; THERMODYNAMICS; THERMOSTABILITY; CHEMISTRY; CONFORMATION; CYCLIZATION; FAST ATOM BOMBARDMENT MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM; X RAY CRYSTALLOGRAPHY;

AZIRIDINES; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; INDICATORS AND REAGENTS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PALLADIUM; SPECTROMETRY, MASS, FAST ATOM BOMBARDMENT; STEREOISOMERISM; THERMODYNAMICS;

EID: 3543124076     PISSN: 00092363     EISSN: 13475223     Source Type: Journal    
DOI: 10.1248/cpb.52.111     Document Type: Article

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