H2O storage capacity of MgSiO3 clinoenstatite at 8-13 GPa, 1,100-1,400°C

Contributions to Mineralogy and Petrology

Volumn 154, Issue 6, 2007, Pages 663-674

  Withers, Anthony C ^a   Hirschmann, M M ^a  

^a UNIVERSITY OF MINNESOTA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ENSTATITE; EXPERIMENTAL MINERALOGY; FTIR SPECTROSCOPY; HIGH PRESSURE; HIGH TEMPERATURE; PARTITIONING; PYROXENE; RAMAN SPECTROSCOPY; WATER;

EID: 35349000693     PISSN: 00107999     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00410-007-0215-7     Document Type: Article

References (60)

1. Angel R, Hugh-Jones D (1994) Equations of state and thermodynamic properties of enstatite pyroxenes. J Geophys Res 99:19777-19783
2. Angel RJ, Chopelas A, Ross NL (1992) Stability of high-density clinoenstatite at upper-mantle pressures. Nature 358:322-324
3. Aubaud C, Hauri EH, Hirschmann MM (2004) Hydrogen partition coefficients between nominally anhydrous minerals and basaltic melts. Geophys Res Lett 31:L20611. doi: 20610.21029/22004GL021341
4. Aubaud C, Withers AC, Hirschmann MM, Guan Y, Leshin LA, Mackwell SJ, Bell DR (2007) Intercalibration of FTIR and SIMS for hydrogen measurements in glasses and nominally anhydrous minerals. Am Mineral 92:811-828. doi: 10.2138/am.2007.2248
5. Bell DR, Rossman GR (1992) Water in Earth's mantle: The role of nominally anhydrous minerals. Science 255:1391-1397
6. Bell DR, Ihinger PD, Rossman GR (1995) Quantitative analysis of trace OH in garnet and pyroxenes. Am Mineral 80:465-474
7. Bell DR, Rossman GR, Maldener J, Endisch D, Rauch F (2003) Hydroxide in olivine: A quantitative determination of the absolute amount and calibration of the IR spectrum. J Geophys Res 108:2105. doi: 2110.1029/ 2001JB000679
8. 2O system up to 24 GPa: Implications for the distribution of water in the Earth's mantle. Earth Planet Sci Lett 182:209-221
9. 3 enstatite. Am Mineral 91:1094-1101
10. Bromiley GD, Keppler H (2004) An experimental investigation of hydroxyl solubility in jadeite and Na-rich clinopyroxenes. Contrib Mineral Petrol 147:189-200
11. Bromiley GD, Keppler H, McCammon C, Bromiley FA, Jacobsen SD (2004) Hydrogen solubility and speciation in natural, gem quality chromian diopside. Am Mineral 89:941-949
12. 4 system. Geophys Res Lett 29:1875. doi: 1810.1029/ 2001GL014429
13. 2O-experimental determination of the stability of Mg-anthophyllite. Am Mineral 70:223-236
14. Dasgupta R, Hirschmann MM, Withers AC (2004) Deep global cycling of carbon constrained by the solidus of anhydrous, carbonated eclogite under upper mantle conditions. Earth Planet Sci Lett 227:73-85
15. Demouchy S, Deloule E, Frost DJ, Keppler H (2005) Pressure and temperature-dependence of water solubility in iron-free wadsleyite. Am Mineral 90:1084-1091
16. Deuss A, Woodhouse JH (2004) The nature of the Lehmann discontinuity from its seismological Clapeyron slopes. Earth Planet Sci Lett 225:295-304
17. Evans BW, Ghiorso MS (1995) Thermodynamics and petrology of cummingtonite. Am Mineral 80:649-663
18. 4 phase transformations in the transition zone. Earth Planet Sci Lett 216:313-318
19. 2O on the 410-km seismic discontinuity. Earth Planet Sci Lett 256:182-195. doi: 10.1016/j.epsl.2007.01.023
20. Ganguly J, Frost DJ (2006) Stability of anhydrous phase B: Experimental studies and implications for phase relations in subducting slab and the X discontinuity in the mantle. J Geophys Res 111:B06203
21. 2O-undersaturated conditions. Earth Planet Sci Lett 248:715-734
22. 2O cycle. Annu Rev Earth Planet Sci 34:629-653
23. 2O in nominally anhydrous minerals in the upper mantle. Earth Planet Sci Lett 236:167-181
24. Hirth G, Kohlstedt DL (1996) Water in the oceanic upper mantle: implications for rheology, melt extraction and the evolution of the lithosphere. Earth Planet Sci Lett 144:93-108
25. Ingrin J, Latrous K, Doukhan JC, Doukhan N (1989) Water in diopside - an electron-microscopy and infrared-spectroscopy study. Eur J Mineral 1:327-341
26. 4: A new water reservoir in the mantle transition region. Geophys Res Lett 22:117-120
27. Irifune T, Isshiki M (1998) Iron partitioning in a pyrolite mantle and the nature of the 410-km seismic discontinuity. Nature 392:702-705
28. Ita J, Stixrude L (1992) Petrology, elasticity, and composition of the mantle transition zone. J Geophys Res 97:6849-6866
29. 4 using Grover, Getting and Kennedy's empirical relation between volume and bulk modulus. Phys Chem Miner 28:72-585
30. 3 -clinopyroxene: Implications for the mantle X-discontinuity. Eos Trans AGU 85(17):U53A-04
31. Jarosewich E, Nelen JA, Norberg JA (1980) Reference samples for electron microprobe analysis. Geostandards Newsl 4:43-47
32. 4. Contrib Mineral Petrol 123:345-357
33. Komabayashi T, Omori S (2006) Internally consistent thermodynamic data set for dense hydrous magnesium silicates up to 35 GPa, 1600 degrees C: implications for water circulation in the Earth's deep mantle. Phys Earth Planet Inter 156:89-107
34. Libowitzky E, Rossman GR (1996) Principles of quantitative absorbance measurements in anisotropic crystals. Phys Chem Miner 23:319-327
35. Libowitzky E, Rossman GR (1997) An IR absorption calibration for water in minerals. Am Mineral 82:1111-1115
36. 3 -clinoenstatite at high pressure. Eos Trans AGU 86(52):MR41A-0899
37. Matsukage KN, Nishihara Y, Karato S (2005) Seismological signature of chemical differentiation of Earth's upper mantle. J Geophys Res 110:B12305. doi: 12310.11029/12004JB003504
38. Mibe K, Fujii T, Yasuda A (2002) Composition of aqueous fluid coexisting with mantle minerals at high pressure and its bearing on the differentiation of the Earth's mantle. Geochim Cosmochim Acta 66:2273-2285
39. Mierdel K, Keppler H (2004) The temperature dependence of water solubility in enstatite. Contrib Mineral Petrol 148:305-311
40. 4 determined by in situ X-ray observation. Science 265:1202-1203
41. Mosenfelder JL, Deligne NI, Asimow PD, Rossman GR (2006) Hydrogen incorporation in olivine from 2-12 GPa. Am Mineral 91:285-294
42. Paterson MS (1982) The determination of hydroxyl by infrared absorption in quartz, silicate glasses and similar materials. Bull Mineral 105:20-29
43. Piermarini GJ, Block S (1975) Ultrahigh pressure diamond-anvil cell and several semiconductor phase transition pressures in relation to fixed point pressure scale. Rev Sci Instrum 46:973-979
44. Rauch M, Keppler H (2002) Water solubility in orthopyroxene. Contrib Mineral Petrol 143:525-536
45. Revenaugh J, Jordan TH (2001) Mantle layering from ScS reverberations.3. The upper mantle. J Geophys Res 96:19781-19810
46. Shinmei T, Tomioka N, Fujino K, Kuroda K, Irifune T (1999) In situ X-ray diffraction study of enstatite up to 12 GPa and 1473 K and equations of state. Am Mineral 84:1588-1594
47. Skogby H, Bell DR, Rossman GR (1990) Hydroxide in pyroxene: Variations in the natural environment. Am Mineral 75:764-774
48. Smyth JR, Frost DJ (2002) The effect of water on the 410-km discontinuity: An experimental study. Geophys Res Lett 29:1485. doi: 1410.1029/2001GL014418
49. Smyth JR, Frost DJ, Nestola F, Holl CM, Bromiley G (2006) Olivine hydration in the deep upper mantle: Effects of temperature and silica activity. Geophys Res Lett 33:L15301. doi: 15310.11029/12006GL026194
50. Smyth JR, Jacobsen SD (2006) Nominally anhydrous minerals and Earth's deep water cycle. In: Jacobsen SD, van der Lee S (eds) Earth's deep water cycle, Geophysical Monograph, vol 168. American Geophysical Union, pp 1-11
51. Stalder R (2004) Influence of Fe, Cr and Al on hydrogen incorporation in orthopyroxene. Eur J Mineralogy 16:703-711
52. Stalder R, Klemme S, Ludwig T, Skogby H (2005) Hydrogen incorporation in orthopyroxene: Interaction of different trivalent cations. Contrib Mineral Petrol 150:473-485
53. Stalder R, Skogby H (2002) Hydrogen incorporation in enstatite. Eur J Mineral 14:1139-1144
54. 2O under upper mantle conditions. Contrib Mineral Petrol 140:607-618
55. 3 orthoenstatite-clinoenstatite transitions at high pressures and temperatures determined by Raman-spectroscopy on quenched samples. Am Mineral 86:1267-1274
56. Williams Q, Hemley RJ (2001) Hydrogen in the deep Earth. Annu Rev Earth Planet Sci 29:365-418
57. Williams Q, Revenaugh J (2005) Ancient subduction, mantle eclogite, and the 300 km seismic discontinuity. Geology 33:1-4
58. Woodland AB (1998) The orthorhombic to high-P monoclinic phase transition in Mg-Fe pyroxenes: Can it produce a seismic discontinuity? Geophys Res Lett 25:1241-1244
59. Yamada A, Inoue T, Irifune T (2004) Melting of enstatite from 13 to 18 GPa under hydrous conditions. Phys Earth Planet Inter 147:45-56
60. 3 at 9-14 GPa. J Geophys Res 98:19785-19793