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19
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35348836991
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note
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2O dissolved in 1 ml water, was added into the solution of lanthanide ions. The mixed liquid was sealed and kept under the temperature of 80 °C for six days. Colorless crystals suitable for X-ray analysis were obtained. Yield of complex 1: 0.1040 g, 37.3% based on the Tb. Elemental analysis (EA): Cacld. for 1: C 27.10, H 3.57, N 4.52. Found: C 27.05, H 3.64, N 4.53.
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20
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35348861708
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note
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2 = 0.1484 (all data), GOF = 1.083.
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21
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0037463049
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Zhao B., Cheng P., Dai Y., Cheng C., Liao D., Yan S., Jiang Z., and Wang G. Angew. Chem., Int. Ed. 42 (2003) 934
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Jiang, Z.7
Wang, G.8
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22
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1642380376
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Zhao B., Cheng P., Chen Y., Cheng C., Wang S., Liao D., Yan S., and Jiang Z. J. Am. Chem. Soc. 126 (2004) 3012
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Jiang, Z.8
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23
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35348812281
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note
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Dehydration of 1: complex 1 was heated at 250 °C in an oven for 2 h to obtain 1a. Adsorption water of 1a: 1a was exposed to a moist environment (by keeping the sample in a double-layer dessicator that contained water in its bottom) for 12 h, and complex 1b was obtained.
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