Modeling of nonlinear effects in pH sensors based on polyelectrolytic hydrogels

Proceedings of SPIE - The International Society for Optical Engineering

Volumn 6524, Issue , 2007, Pages

  Guenther, Margarita ^a   Gerlach, Gerald ^a   Wallmersperger, Thomas ^b  

^a DRESDEN UNIVERSITY OF TECHNOLOGY   (Germany)

^b UNIVERSITY OF STUTTGART   (Germany)

Author keywords

Chemical sensor; Ph sensitive; Polyelectrolytic hydrogel; Swelling behaviour

Indexed keywords

CHEMICAL SENSORS; ENERGY CONVERSION; HYDROPHILICITY; HYSTERESIS; PH; POLYELECTROLYTES; SHRINKAGE; SWELLING;

POLYELECTROLYTIC HYDROGELS; SIGNAL REPRODUCIBILITY;

HYDROGELS;

EID: 35148843726     PISSN: 0277786X     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1117/12.713895     Document Type: Conference Paper

References (27)

1. A.J. Marshall, J. Blyth, C.A.B. Davidson, CR. Lowe, "pH sensitive holographic sensors", Anal. Chem., 75, 4423-4431, 2003.
2. A. Richter, A. Bund, M. Keller, K.-F. Arndt, "Characterization of a microgravimetric sensor based on pH sensitive hydrogels", Sens. Actuat. B, 99 (2-3), 579-585, 2004.
3. R. Bashir, J.Z. Hilt, O. Elibol, A. Gupta, N.A. Peppas, "Micromechanical cantilever as an ultrasensitive pH microsensor", Appl. Phys. Lett. 81, (16), 3091-3093, 2002.
4. S. Herber, J. Eijkel, W. Olthuis, P. Bergveld, A. van den Berg, "Study of chemically induced pressure generation of hydrogels under isochoric conditions using a microfabricated device", J. Chem. Phys., 121, 2746-2751, 2004.
5. G. Gerlach, M. Guenther, G. Suchaneck, J. Sorber, K.-F. Arndt, A. Richter, "Application of sensitive hydrogels in chemical and pH sensors", Macromol. Symp., 210, 403-410, 2004.
6. G. Gerlach M. Guenther, J. Sorber, G. Suchaneck, K.-F. Arndt, A. Richter, "Chemical and pH sensors based on the swelling behavior of hydrogels", Sens. Actuat. B, 111-112, 555-561, 2005.
7. M. Guenther, G. Gerlach, J. Sorber, G. Suchaneck, K.-F. Arndt, A. Richter, "pH sensors based on polyelectrolytic hydrogels", Smart structures and materials: electroactive polymer actuators and devices, Y. Bar-Cohen (ed.), vol. 5759, p.540-548, Proc. SPIE, San Diego, CA, USA, Mar. 7-10, 2005.
8. M. Guenther, D. Kuckling, C. Corten, G. Gerlach, J. Sorber, G. Suchaneck, K.-F. Arndt, "Chemical sensors based on multiresponsive block copolymer hydrogels", Sens. Actuat. B, 2006 (accepted).
9. S. K. De, N. R. Aluru, B. Johnson, W. C. Crone, D. J. Beebe, J. Moore, "Equilibrium swelling and kinetics of pHresponsive hydrogels: models, experiments, and simulations", J. Microelectromech. Syst., 11, 544-555,2002.
10. S. K. De, N. R. Aluru, "A chemo-electro-mechanical mathematical model for simulation of pH sensitive hydrogels", Mechanics of Materials, 36, 395-410, 2004.
11. M. Shahinpoor, K. J. Kim, "Ionic polymer-metal composites: III. Modeling and simulation as biomimetic sensors, actuators, transducers, and artificial muscles", Smart Mater. Struct., 13, 1362-1388,2004.
12. K. M. Newbury, Characterization, Modeling, and Control of Ionic Polymer Transducers, PhD Dissertation, p. 139, Virginia Tech etd-09182002-081047, Blacksburg, Virginia, 2002.
13. K. M. Newbury, D. J. Leo, "Linear electromechanical model of ionic polymer transducers, part I: model development", Intell. Mater. Syst. Struct. 14, 333-342, 2003.
14. T. Wallmersperger, Modellierung und Simulation stimulierbarer polyelektrolytischer Gele, Fortschritt-Berichte VDI, Reihe 5, Nr. 688, VDI-Verlag, Düsseldorf., 2003, p. 142.
15. T. Wallmersperger, B. Kröplin, R. W. Gülch, "Coupled chemo-electro-mechanical formulation for ionic polymer gels - numerical and experimental investigations", Mechanics of Materials, 36, 411-420, 2004.
16. T. Wallmersperger, B. Kröplin, and R. W. Gülch, "Modelling and Analysis of Chemistry and Electromechanics", Electroactive Polymer (EAP) Actuators as Artificial Muscles - Reality, Potential, and Challenges, Second Edition, vol. PM 136, p. 335-362, SPIE Press, Bellingham, WA, USA, 2004.
17. D. J. Leo, K. Farinholt, T. Wallmersperger, "Computational models of ionic transport and electromechanical transduction in ionomeric polymer transducers", Smart structures and materials: electroactive polymer actuators and devices, Y. Bar-Cohen (ed.), vol. 5759, p. 170-181, Proc. SPIE, San Diego, CA, USA, Mar. 7-10, 2005.
18. M. E. G. Lyons (ed.), Electroactive Polymer Electrochemistry. Part 1: Fundamentals, Plenum Press, New York, London, 1994, p. 488.
19. J. W. Gardner, P.N. Bartlett, "Design of conducting polymer gas sensors. Modelling and experiment", Synth. Met., 55-57, 3665-3670, 1993.
20. G. Gerlach, W. Doetzel, Grundlagen der Mikrosystemtechnik, Hanser Verlag, Munich, Vienna, 1997, p. 217.
21. R. Buchhold, Bimorphe Gassensoren, Dresden Univ. Press, Dresden, Munich, 1999, p. 144.
22. A. N. Tikhonov, A. A. Samarskii, Differential Equations of Mathematical Physics, Dover Publ., New York, 1990, p. 660.
23. J. Crank, The Mathematics of Diffusion, London, Oxford Univ. Press, 1970, p. 347.
24. M. Guenther, G. Gerlach, D. Kuckling, K. Kretschmer, C. Corten, J. Weber, J. Sorber, G. Suchaneck, K.-F. Arndt, "Chemical sensors based on temperature-responsive hydrogels", Smart structures and materials 2006: smart sensor monitoring systems and applications, D. Inaudi, W. Ecke, B. Culshaw, K. J. Peters, E. Udd (eds.), vol. 6167, p. 61670T1-61670T1 1, Proc. SPIE, San Diego, CA, USA, Feb. 26 - Mar. 2, 2006.
25. H. S. Carslaw, J. C. Jaeger, Conduction of Heat in Solids, Second edition, Clarendon Press, Oxford, 2005, p.510.
26. R. Changhai, S. Lining, "Hysteresis and creep compensation for piezoelectric actuator in open-loop operation", Sens. Actuat. A, 122, 124-130, 2005.
27. T. Islam, H. Saha, "Hysteresis compensation of a porous silicon relative humidity sensor using ANN technique", Sens. Actuat. B, 114, 334-343, 2006.