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84906391480
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The transition charges for Chl a are given in the Supporting Information of ref 43, and those for Chi b are contained in the Supporting Information of the present work.
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The transition charges for Chl a are given in the Supporting Information of ref 43, and those for Chi b are contained in the Supporting Information of the present work.
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45
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84906377247
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41 The factor of 3.6 D for Chi b was adjusted from the linear spectra of the terodimers and the value for Chl a.
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41 The factor of 3.6 D for Chi b was adjusted from the linear spectra of the terodimers and the value for Chl a.
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84906377248
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In the approach of Hughes et al.29 the dipole strength for Chl a was estimated by integration from the absorption band area to be 19 D2, and the excitonic coupling was screened by a factor 1/ε with ε= 3 such that the effective dipole strength in the coupling calculations is just 2.5 D, much less than the 4.0 D used in the present calculations. However, by coincidence the difference turns out to compensate for the shortcoming of the point-dipole approximation, and therefore the same center-to-center distance was obtained as in the present model
-
2, and the excitonic coupling was screened by a factor 1/ε with ε= 3 such that the effective dipole strength in the coupling calculations is just 2.5 D, much less than the 4.0 D used in the present calculations. However, by coincidence the difference turns out to compensate for the shortcoming of the point-dipole approximation, and therefore the same center-to-center distance was obtained as in the present model.
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84906391477
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For a given ratio x of Chl a/Chl b the respective ratio of Chl a/Chl a homodimers to Chl a/Chl b heterodimers is given as (x -l)/2.
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For a given ratio x of Chl a/Chl b the respective ratio of Chl a/Chl a homodimers to Chl a/Chl b heterodimers is given as (x -l)/2.
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84906406037
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Manuscript submitted for publication
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Theiss, C.; Andree, S.; Schmitt, F. J., Renger, T.; Trostmann, I.; Eichler, H. J.; Paulsen, H.; Renger, G. Manuscript submitted for publication.
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84906377244
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The somewhat larger splitting between the two absorption peaks at 300 K (compared to 77 K in Markoff approximation) is due to the temperature dependence of M.
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The somewhat larger splitting between the two absorption peaks at 300 K (compared to 77 K in Markoff approximation) is due to the temperature dependence of M.
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