New catalytic systems for coupling of dihalogenopyridines and 5,5″-dibromo-2,2′:6′,2″-terpyridine with 5-bromo-2-trialkylstannylpyridines and 2-trialkylstannylthiophenes

Catalysis Communications

Volumn 8, Issue 10, 2007, Pages 1457-1462

  Krompiec, Stanisław ^a   Krompiec, Michał ^a   Ignasiak, Hanna ^a   Łapkowski, Mieczysław ^b   Baj, Stefan ^b   Grabarczyk, Damian ^a  

^a UNIVERSITY OF SILESIA   (Poland)

^b SILESIAN UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

Conjugated polymers; Stille coupling; Terpyridine; Thiophene

Indexed keywords

CONJUGATED POLYMERS; COUPLING AGENTS; LIGANDS; PALLADIUM COMPOUNDS; PYRIDINE; THIOPHENE;

DIHALOGENOPYRIDINES; STILLE COUPLING; TERPYRIDINE; THIENYL-SUBSTITUTED PYRIDINE;

CATALYST ACTIVITY;

EID: 34548503625     PISSN: 15667367     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.catcom.2006.12.013     Document Type: Article

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38. 2 on a rotary evaporator, the residue was sublimated under pressure of 1 mm Hg. Very pure 5,5″-dibromo-2,2′:6′,2″-terpirydine (m.p. 203-204 °C) was obtained with 80% yield.
39. +: 360.04).
40. 3): 64.43, 64.94, 99.47, 113.51, 121.06, 121.22, 129.86, 133.87, 138.02, 139.81, 142.39, 145.57; MS (EI 70 eV): m/z = 513.20 (calc. 513.08).
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