Electropolymerisation dynamics of a highly conducting metallopolymer: Poly-[Os(4′-(5-(2,2′-bithienyl))-2,2′:6′, 2″-terpyridine)2]2+

Electrochemistry Communications

Volumn 6, Issue 2, 2004, Pages 193-200

  Hjelm, Johan ^a   Handel, Robyn W ^b   Hagfeldt, Anders ^a   Constable, Edwin C ^b   Housecroft, Catherine E ^b   Forster, Robert J ^c  

^a UPPSALA UNIVERSITY   (Sweden)

^b UNIVERSITY OF BASEL   (Switzerland)

^c DUBLIN CITY UNIVERSITY   (Ireland)

Author keywords

Charge transport; Conducting polymer; Electropolymerisation; Microelectrode; Redox conduction

Indexed keywords

CHARGE TRANSFER; DIFFUSION; ELECTRODEPOSITION; ELECTRODES; ELECTROPOLYMERIZATION; OXIDATION; PLATINUM; POLYMERS;

CHARGE TRANSPORT; CONDUCTING METALLOPOLYMERS;

ELECTROCHEMISTRY;

PLATINUM; PYRIDINE DERIVATIVE;

ARTICLE; DIFFUSION; ELECTRODE; FILM; MOLECULAR DYNAMICS; OXIDATION; OXIDATION REDUCTION REACTION; POLYMERIZATION; POTENTIOMETRY; SCANNING ELECTRON MICROSCOPY; STATISTICAL ANALYSIS; SURFACE PROPERTY;

EID: 1042302144     PISSN: 13882481     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.elecom.2003.11.011     Document Type: Article

References (28)

1. Wolf M.O. Adv. Mater. 13:2001;545.
2. Pickup P.G. J. Mater. Chem. 9:1999;1641.
3. Kingsborough R.P., Swager T.M. Prog. Inorg. Chem. 48:1999;123.
4. Hjelm J., Handel R.W., Hagfeldt A., Constable E.C., Housecroft C.E., Forster R.J. J. Phys. Chem. B. 107:2003;10431.
5. MacLean B.J., Pickup P.G. J. Phys. Chem. B. 106:2002;4658.
6. Zhu S.S., Swager T.M. J. Am. Chem. Soc. 119:1997;12568.
7. Zhu S.S., Kingsborough R.P., Swager T.M. J. Mater. Chem. 9:1999;2123.
8. Pletcher D., Greef R., Peat R., Peter L.M., Robinson J. Instrumental Methods in Electrochemistry. 1985;Horwood Publishing Ltd, Chichester.
9. Hillman A.R., Mallen E.F. J. Electroanal. Chem. 220:1987;351.
10. Hillman A.R., Mallen E.F. J. Electroanal. Chem. 243:1988;403.
11. John R., Wallace G.G. J. Electroanal. Chem. 306:1991;157.
12. Li F., Albery W.J. Electrochim. Acta. 37:1992;393.
13. Schrebler R., Grez P., Cury P., Veas C., Merino M., Gómez H., Cordova R., del Valle M.A. J. Electroanal. Chem. 430:1997;77.
14. Audebert P., Catel J.-M., Le Coustumer G., Duchenet V., Hapiot P. J. Phys. Chem. B. 102:1998;8661.
15. Randriamahazaka H., Noël V., Chevrot C. J. Electroanal. Chem. 472:1999;103.
16. Abrantes L.M., Correia J.P. Electrochim. Acta. 44:1999;1901.
17. Zotti G., Zecchin S., Schiavon G., Berlin A. J. Electroanal. Chem. 506:2001;106.
18. Roncali J. Chem. Rev. 92:1992;711.
19. Funt B.L. Lund H., Baizer M.M. Organic Electrochemistry: An Introduction and a Guide. third ed. 1991;Marcel Dekker, New York. (Chapter 33).
20. 2] was synthesized according to the general procedure outlined in R.W. Handel, Ph.D. Thesis, University of Birmingham, UK, 2002 (Chapter 3).
21. Forster R.J., Faulkner L.R. J. Am. Chem. Soc. 116:1994;5444.
22. Bard A.J., Faulkner L.R. Electrochemical Methods: Fundamentals and Applications. second ed. 2001;Wiley, New York.
23. Rosvall S.J.M., Sharp M., Bond A. J. Electroanal. Chem. 536:2002;161.
24. Pyathi R., Murray R.W. J. Am. Chem. Soc. 118:1996;1743.
25. 1/2.
26. Niu L., Kvarnström C., Fröberg K., Ivaska A. Synth. Metals. 122:2001;425.
27. Calculated using Eq. (1) and taking n=3 or 4 giving areas 60 or 30 times that of a 12.5 μm radius electrode.
28. dep ) from Fig. 8 in [5].