X-ray spectroscopic and diffraction study of the structure of the active species in the NiII-catalyzed polymerization of isocyanides

ChemPhysChem

Volumn 8, Issue 12, 2007, Pages 1850-1856

  Metselaar, Gerald A ^a   Schwartz, Erik ^a   De Gelder, Rene ^a   Feiters, Martin C ^a   Nikitenko, Serge ^b   Smolentsev, Griqory ^c   Yalovega, Galina E ^c   Soldatov, Alexander V ^c   Cornelissen, Jeroen J L M ^a   Rowan, Alan E ^a   Nolte, Roeland J M ^a  

^a RADBOUD UNIVERSITY NIJMEGEN   (Netherlands)

^b EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

^c SOUTHERN FEDERAL UNIVERSITY   (Russian Federation)

Author keywords

Catalysis; Isocyanide; Nickel; Polymerisation; X ray absorption spectroscopy

Indexed keywords

CATALYSIS; EXTENDED X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; LIGANDS; NICKEL; POLYMERIZATION; X RAY ABSORPTION SPECTROSCOPY;

ACTIVE COMPLEXES; CATALYZED POLYMERIZATION; DIFFRACTION STUDIES; EXTENDED X-RAY ABSORPTION FINE STRUCTURES; ISOCYANIDES; NEAR EDGE STRUCTURE; POLYISOCYANIDES; STRUCTURAL CHARACTERIZATION;

CYANIDES;

EID: 34548414627     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.200700251     Document Type: Article

References (45)

1. a) M. Kauranen, C. Boutton, T. Verbiest, M. N. Teerenstra, K. Clays, A. J. Schouten, R. J. M. Nolte, A. Persoons, Science 1995, 270, 966-969;
2. b) J. J. L. M. Cornelissen, M. Fischer, N. A. J. M. Sommerdijk, R. J. M. Nolte, Science 1998, 280, 1427-1430;
3. c) J. J. L. M. Cornelissen, J. J. M. Donners, R. de Gelder, W. S. Graswinckel, G. A. Metselaar, A. E. Rowan, N. A. J. M. Sommerdijk, R. J. M. Nolte, Science 2001, 293, 676-680;
4. d) D. M. Vriezema, J. Hoogboom, K. Velonia, K. Takazawa, P. C. M. Christianen, J. C. Maan, A. E. Rowan, R. J. M. Nolte, Angew. Chem. 2003, 115, 796-800;
5. Angew. Chem. Int. Ed. 2003, 42, 772-776;
6. e) P. A. J. de Witte, M. Castriciano, J. J. L. M. Cornelissen, L. Monsu Scolaro, R. J. M. Nolte, A. E. Rowan, Chem. Eur. J. 2003, 9, 1775-1781.
7. a) R. J. M. Nolte, Chem. Soc. Rev. 1994, 23, 11-19;
8. b) R. J. M. Nolte, J. W. Zwikker, J. Reedijk, W. Drenth, J. Mol. Catal. 1978, 4, 423-426.
9. J. A. Kanters, H. L. L. M. Nijs, P. van der Sluis, Acta Crystallogr. Sect. C 1989, 45, 16-18.
10. P. C. J. Kamer, R. J. M. Nolte, W. Drenth, J. Am. Chem. Soc. 1988, 110, 6818-6825.
11. a) T. J. Deming, B. M. Novak, Macromolecules 1991, 24, 326-328;
12. b) T. J. Deming, B. M. Novak, J. Am. Chem. Soc. 1993, 115, 9101-9111.
13. D. B. Amabilino, J.-L. Serrano, T. Sierra, J. Veciana, J. Polym. Sci. Part A 2006, 44, 3161-3174.
14. X-ray Absorption Spectroscopy (Eds.: D. C. Koningsberger, R. Prins), Wiley, New York, 1988, pp. 257-320.
15. a) S. P. Cramer, M. K. Eidsness, W.-H. Pan, T. A. Morton, S. W. Ragsdale, D. V. DerVartanian, L. G. Ljungdahl, R. A. Scott, Inorg. Chem. 1987, 26, 2477-2479;
16. b) G. J. Colpas, M. J. Maroney, C. Bagyinka, M. Kumar, W. S. Willis, S. L. Suib, N. Baidya, P. K. Mascharak, Inorg. Chem. 1991, 30, 920-928.
17. a) M. C. Feiters, G. A. Metselaar, B. B. Wentzel, R. J. M. Nolte, S. Nikitenko, D. C. Sherrington, Y. Joly, G. Yu. Smolentsev, A. N. Kravtsova, A. V. Soldatov, Ind. Eng. Chem. Res. 2005, 44, 8631-8640;
18. b) A. V. Soldatov, G. Smolentsev, A. Kravtsova, G. Yalovega, M. C. Feiters, G. A. Metselaar, Y. Joly, Radiat. Phys. Chem. 2006, 75, 1866-1868.
19. a) S. J. Gurman, N. Binsted, I. Ross, J. Phys. C 1986, 19, 1845-1861;
20. b) S. J. Gurman, N. Binsted, I. Ross, J. Phys. C 1984, 17, 143-151.
21. F. C. Rhames, N. N. Murthy, K. D. Karlin, N. J. Blackburn, J. Biol. Inorg. Chem. 2001, 6, 567-577.
22. a) A. J. Dent, J. R. Gouge, G. N. Greaves, A. G. Orpen, Phys. B 1989, 158, 221-222;
23. b) N. Carr, J. G. Crossley, A. J. Dent, J. R. Gouge, G. N. Greaves, P. S. Jarret, A. G. Orpen, J. Chem. Soc. Chem. Commun. 1990, 1369-1371.
24. A. L. Spek (2004) PLATON, A Multipurpose Crystallography Tool, Utrecht University, Utrecht, The Netherlands.
25. P. C. J. Kamer, PhD Thesis, University of Utrecht, The Netherlands, 1987.
26. a) G. Mitchell, W. W. Beeman, J. Chem. Phys. 1952, 20, 1298-1301;
27. b) P. H. Umadikar, S. G. Mestry, N. V. Bhat, B. C. Haldar, Spectrochim. Acta Part B 1976, 31, 411-417;
28. c) N. Kosugi, T. Yokoyama, H. Kuroda, Chem. Phys. 1986, 104, 449-453.
29. N. G. Vannerberg, Acta Chem. Scand. 1964, 18, 2385-2391.
30. A. Bianconi in X-ray Absorption: Principles, Applications and Techniques of EXAFS, SEXAFS and XANES (Eds.: D. C. Koningsberger, R. Prins), Wiley, New York, 1989, pp. 573-662.
31. a) A. L. Ankudinov, C. E. Bouldin, J. J. Rehr, J. Sims, H. Hung, Phys. Rev. B 2002, 65, 104-107;
32. b) A. L. Ankudinov, B. Ravel, J. J. Rehr, S. R. Conradson, Phys. Rev. B 1998, 58, 7565.
33. a) M. Benfatto, A. Congiu-Castellano, A. Daniele, S. Delia Longa, J. Synchrotron Radiat. 2001, 8, 267-269;
34. b) S. Della Longa, S. Pin, R. Cortes, A. Soldatov, B. Alpert, Biophys. J. 1998, 75, 3154-3162.
35. A. M. Rich, R. S. Armstrong, P. J. Ellis, H. C. Freeman, P. A. Lay, Inorg. Chem. 1998, 37, 5743-5753.
36. R. W. Stephany, W. Drenth, Recl. Trav. Chim. Pays-Bas 1972, 91, 1453-1458.
37. M. J. van der Hoek, W. Werner, P. van Zuylen, B. R. Dobson, S. S. Hasnain, J. S. Worgan, G. Luickx, Nucl. Instrum. Methods Phys. Res. Sect. A 1986, 246, 380-384.
38. http://www.esrf.fr/exp_facilities/BM26/domexafsstation.html.
39. http://srs.dl.ac.uk/XRS/Computing/Programs/exback.
40. K. V. Klementiev, VIPER for Windows, freeware: www.desy.de/~klmn/viper.html;
41. K. V. Klementev, J. Phys. D 2001, 34, 209-217.
42. J. J. Rehr, R. C. Albers, Phys. Rev. B 1990, 41, 8139.
43. G. M. Sheldrick, SADABS, Program for Empirical Absorption Correction, University of Goettingen, Germany, 1996.
44. P. T. Beurskens, G. Beurskens, W. P. Bosman, R. Gelder, S. Garcia-Granda, R. O. Gould, R. Israel, J. M. M. Smits, DIDIF-96. A computer program system for crystal structure determination by Patterson methods and direct methods applied to difference structure factors; Crystallography Laboratory, University of Nijmegen: The Netherlands, 1996.
45. G. M. Sheldrick, SHELXL-97. Program for the Refinement of Crystal Structures; University of Goettingen: Germany, 1997.