2,4,6-Trichlorophenyl acrylate emulsion-templated porous polymers (PolyHIPEs). Morphology and reactivity studies

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 45, Issue 17, 2007, Pages 4043-4053

  Leber, Nermina ^a   Fay, Jonathan D B ^b   Cameron, Neil R ^b   Krajnc, Peter ^a  

^a UNIVERSITY OF MARIBOR   (Slovenia)

^b DURHAM UNIVERSITY   (United Kingdom)

Author keywords

2,4,6 trichlorophenyl acrylate; Aryl acrylates; Emulsion polymerization; Emulsion templating; Functionalization of polymers; Macroporous polymers; Monoliths; Morphology; PolyHIPE; Polymer supports; Supports

Indexed keywords

CARBOXYLIC ACIDS; CHEMICAL ANALYSIS; EMULSION POLYMERIZATION; ESTERS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FREE RADICAL POLYMERIZATION; HYDROLYSIS; SCANNING ELECTRON MICROSCOPY; TOLUENE;

ARYL ACRYLATES; EMULSION TEMPLATING; FUNCTIONALIZATION OF POLYMERS; HIGH INTERNAL PHASE EMULSIONS (HIPE); MERCURY INTRUSION POROSIMETRY; MONOLITHIC CROSSLINKED POLYMERS; POLYMER SUPPORTS; POROGENIC SOLVENT;

POLYMERS;

EID: 34548244048     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.22158     Document Type: Article

References (49)

1. Merrifield, R. B. J Am Chem Soc 1963, 85, 2149-2154.
2. Dörwald, F. Z. Organic Synthesis on Solid Phase: Supports, Linkers, Reactions; Wiley-VCH: Weinheim, 2002.
3. Ley, S. V.; Baxendale, I. R.; Bream, R. N.; Jackson, P. S.; Leach, A. G.; Longbottom, D. A.; Nesi, M.; Scott, J. S.; Storer, R. I.; Taylor, S. J. J Chem Soc Perkin Trans 2000, 1, 3815-4195.
4. Sherrington, D. C.; Hodge, P. Syntheses and Separations Using Functional Polymers; Wiley: Chichester, 1988.
5. Hodge, P. Chem Soc Rev 1997, 26, 417-424.
6. The term "channeling" is used to describe the by pass of the flow in a column.
7. Rodrigues, A. E.; Lu, Z. P.; Loureiro, J. M.; Carta, G. J Chromatogr 1993, 653, 189-198.
8. Hodge, P. Ind Eng Chem Res 2005, 44, 8542-8553.
9. (a) Tripp, J. A.; Stein, J. A.; Svec, F.; Fréchet, J. M. J Org Lett 2000, 2, 195-198;
10. (b) Tripp, J. A.; Svec, F.; Fréchet, J. M. J. J Comb Chem 2001, 3, 216-223.
11. Kubin, M.; Spacek, P.; Chromecek, R. Coll Czechosl Chem Commun 1967, 32, 3881-3887.
12. Tennikova, T. B.; Svec, F.; Belenkii, B. G. High-performance membrane chromatography-a novel method of protein separation. J Liquid Chromatogr 1990, 13, 63-70.
13. BIA Separations Ljubljana, Slovenia. http://www.monoliths.com
14. Ley, S. V.; Baxendale, I. R. Nature Rev Drug Disc 2002, 1, 573-586.;
15. (b) Kirschning, A.; Solodenko, W.; Mennecke, K. Chem Eur J 2006, 12, 5972-5990.
16. Cameron, N. R. In Monolithic Materials: Preparation, Properties and Applications; Svec, F.; Tehnikova, T. B.; Deyl, Z., Eds.; Elsevier Science: Amsterdam, 2003.
17. (a) Williams, J. M.; Gray, A. J.; Wilkerson, M. H. Langmuir 1990, 6, 437-444;
18. (b) Duke, J. R.; Hoisington, M. A.; Langlois, D. A.; Benicewicz, B. C. Polymer 1998, 39, 4369-4378;
19. (c) Williams, J. M.; Bartos, J. J.; Wilkerson, M. H. J Mater Sci 1990, 25, 5134-5141.
20. 74% represents the maximum volume occupiable by uniform, underformed spheres. The term Poly-HIPE was first used by Unilever researchers. Eur Pat060138, 1982; Barby, D.; Haq, Z..
21. Alexandratos, S. D.; Beauvais, R.; Duke, J. R.; Jorgensen, B. S. J Appl Polym Sci 1998, 68 1911-1916.
22. Walsh, D. C.; Stenhouse, J. I. T.; Kingsbury, L. P.; Webster, E. J. J Aerosol Sci 1996, 27, 629-630.
23. Cameron, N. R.; Sherrington, D. C.; Ando, I.; Kurosu, H. J Mater Chem 1996, 6, 719-726.
24. Schoo, H. F. M.; Challa, G.; Rowatt, B.; Sherrington, D. C. React Polym 1992, 16, 125-136.
25. (a) Hayman, M. W.; Smith, K. H.; Cameron, N. R.; Przyborski, S. A. Biochem Biophys Res Commun 2004, 314, 483-488;
26. (b) Hayman, M. W.; Smith, K. H.; Cameron, N. R.; Przyborski, S. A. J Biophys Biochem Methods 2005, 62, 231-240.
27. (a) Mercier, A.; Deleuze, H.; Mondain-Monval, O. React Funct Polym 2000, 46, 67-79;
28. (b) Mercier, A.; Deleuze, H.; Mondain-Monval, O. Macrom Chem Phys 2001, 202, 2672-2680.
29. (a) Barbetta, A.; Cameron, N. R.; Cooper, S. J. Chem Commun 2000, 3, 221-222;
30. (b) Benicewicz, B. C.; Jarvinen, G. D.; Kathios, D. J.; Jorgensen, B. S. 1998, 235, 31-35.
31. Krajnc, P.; Brown, J. F.; Cameron, N. R. Org Lett J Radioanal Nucl Chem 2002, 4, 2497-2500.
32. Krajnc, P.; Leber, N.; Štefanec, D.; Kontrec, S.; Podgornik, A. J Chromatogr A 2005, 1065, 69-73.
33. Zupan, M.; Krajnc, P.; Stavber, S. Polymer 1996, 37, 5477-5481.
34. Krajnc, P.; Toplak, R. React Funct Polym 2002, 52, 11-18.
35. Krajnc, P.; Štefanec, D.; Brown, J. F.; Cameron, N. R. J Polym Sci Part A: Polym Chem 2005, 43, 296-303.
36. Narasimhaswamy, T.; Murthy, N. T.; Sumathi, S. C.; Reddy, B. S. R. Angew Makrom Chem 1993, 213, 21-32.
37. (a) Zupan, M.; Krajnc, P.; Trnovšek, R.; Stavber, S. Acta Chim Slov 1996, 43, 189-205;
38. (b) Zupan, M.; Krajnc, P.; Stavber, S. J Polym Sci Part A: Polym Chem 1996, 34, 2325-2331.
39. (a) Zupan, M.; Krajnc, P.; Stavber, S. J Polym Sci Part A: Polym Chem 1998, 36, 1699-1706;
40. (b) Zupan, M.; Krajnc, P.; Stavber, S. Acta Chim Slov 1998, 45, 429-442.
41. Attwood, D.; Florence, A. T. Surfactant Systems: Their Chemistry, Pharmacy and Biology; Chapman and Hall: New York, 1983.
42. Cameron, N. R.; Sherrington, D. C.; Albiston, L.; Gregory, D. P. Coll Polym Sci 1996, 274, 592-95.
43. Cameron, N. R.; Barbetta, A. J Mater Chem 2000, 10, 2466-2472.
44. (a) Hainey, P.; Huxham, I. M.; Rowatt, B.; Sherrington, D. C.; Tetley, L. Macromolecules 1991, 24, 117-121;
45. (b) Barbetta, A.; Cameron, N. R. Macromolecules 2004, 37, 3188-3201;
46. (c) Barbetta, A.; Cameron, N. R. Macromolecules 2004, 37, 3202-3213.
47. Carnachan, R. J.; Bokhari, M.; Przyborski, M.; Cameron, N. R. Soft Matter 2006, 2, 337-342.
48. Booth, R. J.; Hodges, J. C. J Am Chem Soc 1997, 119, 4882-4886.
49. Krajnc, P.; Štefanec, D.; Pulko, I. Macromol Rapid Commun 2005, 26, 1289-1293.