High internal phase emulsions (HIPEs) containing divinylbenzene and 4- vinylbenzyl chloride and the morphology of the resulting PolyHIPE materials

Chemical Communications

Volumn , Issue 3, 2000, Pages 221-222

  Barbetta, Andrea ^a   Cameron, Neil R ^a   Cooper, Sharon J ^a  

^a DURHAM UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

POLYMER; STYRENE DERIVATIVE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL STRUCTURE; EMULSION; HYDROPHOBICITY; MATERIAL STATE; SCANNING ELECTRON MICROSCOPY;

EID: 0034615078     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a909060f     Document Type: Article

References (27)

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3. N. R. Cameron and D. C. Sherrington, Colloid Polym. Sci., 1996, 274, 592; N. R. Cameron, D. C. Sherrington, I. Ando and H. Kurosu, J. Mater. Chem., 1996, 6, 719; N. R. Cameron and D. C. Sherrington, Macromolecules, 1997, 30, 5860; N. R. Cameron and D. C. Sherrington, J. Mater. Chem., 1997, 7, 2209.
4. N. R. Cameron and D. C. Sherrington, Colloid Polym. Sci., 1996, 274, 592; N. R. Cameron, D. C. Sherrington, I. Ando and H. Kurosu, J. Mater. Chem., 1996, 6, 719; N. R. Cameron and D. C. Sherrington, Macromolecules, 1997, 30, 5860; N. R. Cameron and D. C. Sherrington, J. Mater. Chem., 1997, 7, 2209.
5. N. R. Cameron and D. C. Sherrington, Colloid Polym. Sci., 1996, 274, 592; N. R. Cameron, D. C. Sherrington, I. Ando and H. Kurosu, J. Mater. Chem., 1996, 6, 719; N. R. Cameron and D. C. Sherrington, Macromolecules, 1997, 30, 5860; N. R. Cameron and D. C. Sherrington, J. Mater. Chem., 1997, 7, 2209.
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15. K. Jones, B.R. Lothian, A. Martin, G. Taylor and Z. Haq, U.S. Pat. 4,668,709, 1987; H. F. M. Schoo, G. Challa, B. Rowatt and D. C. Sherrington, React. Polym., 1991/1992, 16, 125; B. C. Benicewicz, G. D. Jarvinen, D. J. Kathios and B. S. Jorgensen, J. Radioanal. Nucl. Chem., 1998, 235, 31; S. D. Alexandratos, R. Beauvais, J. R. Duke and B. S. Jorgensen, J. Appl. Polym. Sci., 1998, 68, 1911.
16. K. Jones, B.R. Lothian, A. Martin, G. Taylor and Z. Haq, U.S. Pat. 4,668,709, 1987; H. F. M. Schoo, G. Challa, B. Rowatt and D. C. Sherrington, React. Polym., 1991/1992, 16, 125; B. C. Benicewicz, G. D. Jarvinen, D. J. Kathios and B. S. Jorgensen, J. Radioanal. Nucl. Chem., 1998, 235, 31; S. D. Alexandratos, R. Beauvais, J. R. Duke and B. S. Jorgensen, J. Appl. Polym. Sci., 1998, 68, 1911.
17. K. Jones, B.R. Lothian, A. Martin, G. Taylor and Z. Haq, U.S. Pat. 4,668,709, 1987; H. F. M. Schoo, G. Challa, B. Rowatt and D. C. Sherrington, React. Polym., 1991/1992, 16, 125; B. C. Benicewicz, G. D. Jarvinen, D. J. Kathios and B. S. Jorgensen, J. Radioanal. Nucl. Chem., 1998, 235, 31; S. D. Alexandratos, R. Beauvais, J. R. Duke and B. S. Jorgensen, J. Appl. Polym. Sci., 1998, 68, 1911.
18. P. Hainey, I. M. Huxham, B. Rowatt and D. C. Sherrington, Macromolecules, 1991, 24, 117.
19. Commercial grade DVB used in this study contains 80% actual DVB, the remainder being a mixture of ethylstyrene isomers.
20. J. M. Williams, A. J. Gray and M. H. Wilkerson, Langmuir, 1990, 6, 437.
21. Viscosities of VBC and DVB (55%) at 25°C are 1.830 and 1.007; from: Kirk-Othmer Encyclopedia of Chemical Technology, 4th edn., ed. J. I. Kroschwitz, Wiley, New York, 1991.
22. D. Myers, Surfactant Science and Technology, VCH, Weinheim, 1988, p. 228.
23. M. J. Rosen, Surfactants and Interfacial Phenomena, 2nd edn., Wiley, 1989, p. 6.
24. -3).
25. J. M. Williams, Langmuir, 1991, 7, 1370.
26. One example, Brij 78, was found to produce a bimodal cell size distribution, the smaller of which were smaller than those commonly observed in S/DVB foams.
27. PolyHIPE coding system: VaXbPVc, a = wt. % of VBC relative to total monomer phase; b = nominal crosslink density (wt. % of actual DVB in monomer phase); c = pore volume (vol. % internal phase of HIPE).