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Volumn 46, Issue 17, 2007, Pages 6831-6833

Delocalized mixed-valence bi- and trinuclear complexes with short Cu-Cu bonds

Author keywords

[No Author keywords available]

Indexed keywords

ACETAMIDE DERIVATIVE; COPPER; LIGAND; METALLOPROTEIN; ORGANOMETALLIC COMPOUND; PYRIDINE DERIVATIVE;

EID: 34548233646     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic7010474     Document Type: Article
Times cited : (24)

References (37)
  • 1
    • 33744949169 scopus 로고    scopus 로고
    • Messerschmidt, A, Huber, R, Poulos, T, Wieghardt, K, Eds, Wiley: New York
    • Magnus, K. A. In Handbook of Metalloproteins; Messerschmidt, A., Huber, R., Poulos, T., Wieghardt, K., Eds.; Wiley: New York, 2001; Vol. 2, pp 1303-1318.
    • (2001) Handbook of Metalloproteins , vol.2 , pp. 1303-1318
    • Magnus, K.A.1
  • 4
    • 0037683397 scopus 로고    scopus 로고
    • Messerschmidt, A, Huber, R, Poulos, T, Wieghardt, K, Eds, Wiley: New York
    • (a) Eicken, C.; Gerdemann, C.; Krebs, B. In Handbook of Metalloproteins; Messerschmidt, A., Huber, R., Poulos, T., Wieghardt, K., Eds.; Wiley: New York, 2001; Vol. 2, pp 1319-1329.
    • (2001) Handbook of Metalloproteins , vol.2 , pp. 1319-1329
    • Eicken, C.1    Gerdemann, C.2    Krebs, B.3
  • 6
    • 2142765992 scopus 로고    scopus 로고
    • Messerschmidt, A, Huber, R, Poulos, T, Wieghardt, K, Eds, Wiley: New York
    • Messerschmidt, A. In Handbook of Metalloproteins; Messerschmidt, A., Huber, R., Poulos, T., Wieghardt, K., Eds.; Wiley: New York, 2001; Vol. 2, pp 1345-1358.
    • (2001) Handbook of Metalloproteins , vol.2 , pp. 1345-1358
    • Messerschmidt, A.1
  • 30
    • 34548266957 scopus 로고    scopus 로고
    • See the Supporting Information for synthetic details and characterization
    • See the Supporting Information for synthetic details and characterization.
  • 32
    • 34548274795 scopus 로고    scopus 로고
    • iso = 77 G.
    • iso = 77 G.
  • 33
    • 34548257579 scopus 로고    scopus 로고
    • X-ray data collection was performed on a Bruker Apex CCD diffractometer with Mo Kα radiation (0.710 73 Å) at 120 K for 1 and 100 K for 2a and 2b. X-ray data for 1: C17H 18Cu2F3N4O5S, M, 574.49, monoclinic, space group C2/c, a, 27.741(6) Å, b, 11.365(2) Å, c, 13.468(3) Å, β, 102.735(2)°, V, 4141.7(14) Å3, Z, 8, ρcalcd, 1.843 g/cm3, R1, 0.0566, wR2, 0.0820, GOF, 1.030. X-ray data for 2a: C31H44Cu3F3N6NaO 8S, M, 931.39, orthorhombic, space group Pccn, a, 22.117(3) Å, b, 15.280(2) Å, c, 21.380(3) Å, V, 7225.3(17) Å3, Z, 8, ρcalcd, 1.712 g/cm3, R1, 0.0284, wR2, 0.0770, GOF, 1.005. X-ray data for 2b: C
    • 3, R1 = 0.0567, wR2 = 0.1140, GOF = 1.002.
  • 34
    • 34548268420 scopus 로고    scopus 로고
    • Polymorph 2a is comprised of double-stranded chains of Cu trimers linked via the amidate O atoms and Na cations (Figure S3 in the Supporting Information), while 2b forms 2D sheets of trimers connected via amidate O atoms to NaOTf nodes (Figure S4 in the Supporting Information).
    • Polymorph 2a is comprised of double-stranded chains of Cu trimers linked via the amidate O atoms and Na cations (Figure S3 in the Supporting Information), while 2b forms 2D sheets of trimers connected via amidate O atoms to NaOTf nodes (Figure S4 in the Supporting Information).


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