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In the nitrite anion NO2- that represents the limiting case with complete electron transfer, the νa(NO 2) and νs(NO2) are close to each other, 16 with νa(NO2) even lower than νsNO2
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2).
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43
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34548290221
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In the NO2 molecule, the ONO angle is equal to 134°, whereas in the nitrite anion it is 115°, and intermediate values were obtained for the structurally characterized nitro complexes of the cobalt- and iron-porphyrins. The calculated value of the ONO angle for the Co(TPP)(NO 2) complex is 124.4°.22
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