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Abbreviations: 18C6, 1,4,7,10,13,16-hexaoxacyclooctadecane; DMF, N, N′-dimethylformamide; K(222), potassium complex of 4,7,13,16,-21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane; Mb, ferrous myoglobin; metMb, ferric myoglobin; OEP, dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin; TPP, dianion of 5,10,15,20-tetraphenylporphyrin; TpivPP, dianion of α,α,α,α -tetrakis(o-pivalamidophenyl)porphyrin.
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2)], in addition to the six-coordinate bis(nitro) complex.
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