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Volumn 26, Issue 17, 2007, Pages 4094-4097

A discrete ortho-lithiated acetophenone imine derivative: Isolation, characterization, and synthesis of group IV metal complexes

Author keywords

[No Author keywords available]

Indexed keywords

DERIVATIVES; LIGANDS; METAL COMPLEXES; ORGANOMETALLICS; SYNTHESIS (CHEMICAL); TITANIUM COMPOUNDS; ZIRCONIUM COMPOUNDS;

EID: 34548146303     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om700530z     Document Type: Article
Times cited : (10)

References (46)
  • 27
    • 0000303395 scopus 로고    scopus 로고
    • An earlier report details the synthesis of a related aldimine species (3′,4′-methylenedioxybenzaldehyde cyclohexyl imine) and its in situ lithiation, as determined by quenching experiments: Ziegler, F. E, Fowler, K. W. J. Org. Chem. 1976, 41, 1564
    • An earlier report details the synthesis of a related aldimine species (3′,4′-methylenedioxybenzaldehyde cyclohexyl imine) and its in situ lithiation, as determined by quenching experiments: Ziegler, F. E.; Fowler, K. W. J. Org. Chem. 1976, 41, 1564.
  • 28
    • 34548154156 scopus 로고    scopus 로고
    • 2 isomer with ligand carbon donor atoms in a trans orientation was ascribed to the more stable isomer on the basis of the crystal structure of the dialkylated species 4, detailed below.
    • 2 isomer with ligand carbon donor atoms in a trans orientation was ascribed to the more stable isomer on the basis of the crystal structure of the dialkylated species 4, detailed below.
  • 29
    • 34548176946 scopus 로고    scopus 로고
    • 6, 400 MHz) δ 7.14-7.01 (m, 6H), 6.90 (d, 2H, 8 Hz), 6.58 (d, 2H, 8 Hz), 5.32 (s, 4H), 2.59 (s, 6H), 2.56-2.38 (m, 8H), 1.75 (s, 6H), 1.15 (t, 12H, 8 Hz).
    • 6, 400 MHz) δ 7.14-7.01 (m, 6H), 6.90 (d, 2H, 8 Hz), 6.58 (d, 2H, 8 Hz), 5.32 (s, 4H), 2.59 (s, 6H), 2.56-2.38 (m, 8H), 1.75 (s, 6H), 1.15 (t, 12H, 8 Hz).
  • 30
    • 34548189168 scopus 로고    scopus 로고
    • Crystal data: C46H62N2O 4Si2Zr·1/2C4H10O, triclinic, P1̄, a, 11.4685(6) Å, b, 12.6056(6) Å, c, 18.3425(9) Å, α, 81.983(1)°, β= 77.081(1)°, γ, 65.461(1)°, T, 138 °C, R1, 0.068, wR2, 0.199 all data
    • 10O, triclinic, P1̄, a = 11.4685(6) Å, b = 12.6056(6) Å, c = 18.3425(9) Å, α = 81.983(1)°, β= 77.081(1)°, γ = 65.461(1)°, T = -138 °C, R1 = 0.068, wR2 = 0.199 (all data).
  • 35
    • 34548171609 scopus 로고    scopus 로고
    • 6).
    • 6).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.