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Volumn 9, Issue 31, 2007, Pages 4269-4274

Diazo chemistry controlling the selectivity of olefin ketonisation by nitrous oxide

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; CARBON; KETONE; NITROGEN; NITROUS OXIDE; OXADIAZOLE DERIVATIVE; OXYGEN;

EID: 34547683256     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/b704351a     Document Type: Article
Times cited : (32)

References (40)
  • 22
    • 34547680433 scopus 로고    scopus 로고
    • See ESI
    • See
  • 34
    • 34547667445 scopus 로고    scopus 로고
    • -1. Clearly, the formation of carbene will be favoured
    • -1. Clearly, the formation of carbene will be favoured
  • 35
    • 34547663737 scopus 로고    scopus 로고
    • 2 group to the carbonyl O-atom was reported earlier to face a higher barrier than the addition with the terminal N-atom to the carbonyl O-atom reconstituting the OD.16b
    • 2 group to the carbonyl O-atom was reported earlier to face a higher barrier than the addition with the terminal N-atom to the carbonyl O-atom
  • 36
    • 34547660613 scopus 로고    scopus 로고
    • 2-C atoms (substituted C: +0.06, non-substituted C: -0.22); calculated Mulliken charges at the UCCSD(T)/6-31G(d)//B3LYP-DFT/6-311++G(d,p)- level
    • 2-C atoms (substituted C: +0.06, non-substituted C: -0.22); calculated Mulliken charges at the UCCSD(T)/6-31G(d)//B3LYP-DFT/6-311++G(d,p)- level
  • 37
    • 34547653102 scopus 로고    scopus 로고
    • A methyl shift was already suggested in the ketonization of 2,3-dimethylbut-2-ene by Buckley, 1b in order to explain the formation of 3,3-dimethylbutan-2-one
    • A methyl shift was already suggested in the ketonization of 2,3-dimethylbut-2-ene by
  • 38
    • 34547660615 scopus 로고    scopus 로고
    • 2O at higher temperature. 2e Indeed, for cyclohexene this channel is usually much slower than the competing H-shift; only at elevated temperatures can competition take place
    • Such a rearrangement of the backbone has also been observed by Panov et al. during the gas phase ketonization of cyclohexene with


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.