Hypercoordinate diorganosilanes featuring an (ONO) tridentate ligand. A surprising equilibrium between penta- And tetracoordination

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

Volumn 62, Issue 2, 2007, Pages 225-234

  Wagler, Jörg ^a   Brendler, Erica ^a  

^a TU BERGAKADEMIE FREIBERG   (Germany)

Author keywords

Allyl; Chelate; Equilibrium; Hypercoordination; Silicon

Indexed keywords

CHLORINE COMPOUNDS; ISOMERS; LIGANDS; PHASE EQUILIBRIA; SILICON;

ALLYL; CHELATE; CHLOROFORM SOLUTIONS; HYPERCOORDINATION; PENTA-COORDINATE SILICONS; PENTACOORDINATE SILICON ATOM; PENTACOORDINATED; TRIDENTATE LIGANDS;

SILICON COMPOUNDS;

EID: 34547450611     PISSN: 09320776     EISSN: None     Source Type: Journal    
DOI: 10.1515/znb-2007-0214     Document Type: Article

References (33)

1. C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371.
2. A. Kolomeitsev, G. Bissky, E. Lork, V. Movchun, E. Rusanov, P. Kirsch, G.-V. Röschenthaler, Chem. Commun. 1999, 1107.
3. a) E. P. A. Couzijn, M. Schakel, F. J. J. de Kanter, A. W. Ehlers, M. Lutz, A. L. Spek, K. Lammertsma, Angew. Chem. 2004, 116, 3522;
4. Angew. Chem., Int. Ed. 2004, 43, 3440;
5. b) S. Deerenberg, M. Schäkel, A. H. J. F. de Keijzer, M. Kranenburg, M. Lutz, A. L. Spek, K. Lammertsma, Chem. Commun. 2002, 348.
6. a) M. E. Mowery, P. DeShong, J. Org. Chem. 1999, 64, 3266;
7. b) C. Wolf, R. Lerebours, Org. Lett. 2004, 6, 1147;
8. c) S. Riggleman, P. DeShong, J. Org. Chem. 2003, 68, 8106;
9. d) W. M. Seganish, P. DeShong, J. Org. Chem. 2004, 69, 1137;
10. e) S. E. Denmark, R. F. S weis, Ace Chem. Res. 2002, 35, 835.
11. a) N. Kano, M. Yamamura, T. Kawashima, J. Am. Chem. Soc. 2004, 126, 6250;
12. b) N. Aoyama, T. Hamada, K. Manabe, S. Kobayashi, J. Org. Chem. 2003, 68, 7329;
13. c) A. V. Malkov, M. Orsini, D. Pernazza, K. W. Muir, V. Langer, P. Meghani, P. Kocovský, Org. Lett. 2002, 4, 1047;
14. d) M. Kira, T. Taki, H. Sakurai, J. Org. Chem. 1989, 54, 5674;
15. e) M. Kira, K. Sato, H. Sakurai, J. Am. Chem. Soc. 1990, 112, 257;
16. f) M. Kira, L. C. Zhang, C. Kabuto, H. Sakurai, Organometallics 1998, 17, 887.
17. J. Wagler, T. Doert, G. Roewer, Angew. Chem. 2004, 116, 2495;
18. Angew. Chem. Int. Ed. 2004, 43, 2441.
19. a) I. Kalikhman, B. Govstevskii, M. Botoshansky, M. Kaftory, C. A. Tessier, M. J. Panzner, W. J. Youngs, D. Kost, Organometallics 2006, 25, 1252;
20. b) D. Kost, V. Kingston, B. Gostevskii, A. Ellern, D. Stalke, B. Walfort, I. Kalikhman, Organometallics 2002, 27, 2293;
21. c) D. Kost, V. Kingston, B. Gostevskii, V. Pestunovich, D. Stalke, B. Walfort, I. Kalikhman, Organometallics 2002, 21, 4468.
22. a) J. Wagler, G. Roewer, Z. Naturforsch. 2005, 60b, 709;
23. b) J. Wagler, U. Böhme, E. Brendler, S. Blaurock, G. Roewer, Z. Anorg. Allg. Chem. 2005, 631, 2907.
24. J. Wagler, G. Roewer, Z. Naturforsch. 2006, 61b, 1406.
25. J. Wagler, U. Böhme, E. Brendler, G. Roewer, Organometallics 2005, 24, 1348.
26. J. Wagler, Organometallics 2007, 26, in press.
27. J. Wagler, U. Böhme, E. Brendler, G. Roewer, Z. Naturforsch. 2004, 59b, 1348.
28. O. Seiler, C. Burschka, S. Metz, M. Penka, R. Tacke, Chem. Eur. J. 2005, 11, 7379.
29. a) T. K. Prakasha, A. Chandrasekaran, R. O. Day, R. R. Holmes, Inorg. Chem. 1996, 35, 4342;
30. b) E. Gómez, V. Santes, V. de la Luz, N. Farfán, J. Organomet. Chem. 1999, 590, 237;
31. c) E. Gómez, V. Santes, V. de la Luz, N. Farfán, J. Organomet. Chem. 2001, 622, 54.
32. R. Atkins, G. Brewer, E. Kokot, G. M. Mockler, E. Sinn, Inorg. Chem. 1985, 24, 127.
33. For explanation of SAME and SADI restraints see the SHELX-97 manual.