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Volumn 26, Issue 14, 2007, Pages 3336-3345

Stereoselective "electrophilic" cyclometalation of planar-prochiral (η6-arene)tricarbonylchrommm complexes with asymmetric metal centers: Pseudo-T-4 [Cp*RhCl2]2 and [Cp*IrCl2]2

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; REACTION KINETICS; SODIUM COMPOUNDS; STEREOSELECTIVITY; X RAY DIFFRACTION ANALYSIS;

EID: 34547380846     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om070170l     Document Type: Article
Times cited : (91)

References (137)
  • 40
    • 34547313389 scopus 로고    scopus 로고
    • Zipp, G. Ph.D. Dissertation, University of California, Irvine, 2001; UMI microforms, Ann Arbor, no. 9993250.
    • (d) Zipp, G. Ph.D. Dissertation, University of California, Irvine, 2001; UMI microforms, Ann Arbor, no. 9993250.
  • 61
    • 0036172891 scopus 로고    scopus 로고
    • Leading reviews: (a) Berger, A.; Djukic, J.-P.; Michon, C. Coord. Chem. Rev. 2002, 225, 215-238.
    • Leading reviews: (a) Berger, A.; Djukic, J.-P.; Michon, C. Coord. Chem. Rev. 2002, 225, 215-238.
  • 63
    • 0001249451 scopus 로고
    • Abel, E. W, Stone, F. G. A, Wilkinson, G, Eds, Pergamon; Oxford
    • (c) Morris, M. J. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A, Wilkinson, G., Eds.: Pergamon; Oxford, 1995; Vol. 5, pp 471-549.
    • (1995) Comprehensive Organometallic Chemistry II , vol.5 , pp. 471-549
    • Morris, M.J.1
  • 96
    • 0009540801 scopus 로고    scopus 로고
    • Chirality descriptors for so-called planar-chiral molecules are generally defined by ad hoc sequence rules that depend upon the nature of the considered molecule. The authors would like to point out that despite the sustained efforts of the IUPAC to unify both the terminology of stereochemistry and the nomenclature of chiral molecules, two definitions of chirality descriptors for metallocenic planar-chirality, which are based on different perceptions of planar-chirality itself, still coexist and can be found in the literature. The first one is based on Schlögl's first nomenclature, which was proposed in 1964 in two consecutive reports; it is based on the determination of the succession of the aromatic ring's substituents (either clockwise (R) or anti-clockwise S, by order of decreasing priority, as the molecule is observed from its principal axis perpendicularly to the aromatic ligand's plane, the π-bonded metal sitting underneath the plane. The second one is an exten
    • Chirality descriptors for so-called planar-chiral molecules are generally defined by ad hoc sequence rules that depend upon the nature of the considered molecule. The authors would like to point out that despite the sustained efforts of the IUPAC to unify both the terminology of stereochemistry and the nomenclature of chiral molecules, two definitions of chirality descriptors for metallocenic planar-chirality, which are based on different perceptions of planar-chirality itself, still coexist and can be found in the literature. The first one is based on Schlögl's first nomenclature, which was proposed in 1964 in two consecutive reports; it is based on the determination of the succession of the aromatic ring's substituents (either clockwise (R) or anti-clockwise (S)), by order of decreasing priority, as the molecule is observed from its principal axis perpendicularly to the aromatic ligand's plane, the π-bonded metal sitting underneath the plane. The second one is an extension of the Cahn-Ingold-Prelog (abbreviated CIP) priority, or sequence, rule proposed in 1967 again by Schlögl, who recommended it in place of his first nomenclature: "We shall therefore in the future make use of the nomenclature proposed by Cahn, Ingold and Prelog...". Throughout the present article this extended CIP sequence rule is used to assign the pS or the pR stereochemical descriptors to planar chiral molecules. Readers are referred to the following references for more details: (a) Schlögl, K.; Fried, M. Monatsh. Chem. 1964, 95, 558-575.
  • 100
    • 2742535506 scopus 로고    scopus 로고
    • For IUPAC's basic terminology of stereochemistry see
    • For IUPAC's basic terminology of stereochemistry see: Moss, G. P. Pure Appl. Chem. 1996, 68, 2193-2222.
    • (1996) Pure Appl. Chem , vol.68 , pp. 2193-2222
    • Moss, G.P.1
  • 128
    • 0036589224 scopus 로고    scopus 로고
    • (a) Paley, R. S. Chem. Rev. 2002, 102, 1493-1523.
    • (2002) Chem. Rev , vol.102 , pp. 1493-1523
    • Paley, R.S.1
  • 136
    • 34547288764 scopus 로고    scopus 로고
    • Frisch, M. J, Trucks, G. W, Schlegel, H. B, Scuseria, G. E, Robb, M. A, Cheeseman, J. R, Zakrzewski, V. G, Montgomery, J. A, Jr, Stratmann, R. E, Burant, J. C, Dapprich, S, Millam, J. M, Daniels, A. D, Kudin, K. N, Strain, M. C, Farkas, O, Tomasi, J, Barone, V, Cossi, M, Cammi, R, Mennucci, B, Pomelli, C, Adamo, C, Clifford, S, Ochterski, J, Petersson, G. A, Ayala, P. Y, Cui, Q, Morokuma, K, Malick, D. K, Rabuck, A. D, Raghavachari, K, Foresman, J. B, Cioslowski, J, Ortiz, J. V, Stefanov, B. B, Liu, G, Liashenko, A, Piskorz, P, Komaromi, I, Gomperts, R, Martin, R. L, Fox, D. J, Keith, T, Al-Laham, M. A, Peng, C. Y, Nanayakkara, A, Gonzalez, C, Challacombe, M, Gill, P. M. W, Johnson, B, Chen, W, Wong, M. W, Andres, J. L, Gonzalez, C, Head-Gordon, M, Replogle, E. S, Pople, J. A. Gaussian 98, Revision A.6; Gaussian Inc, Pittsburgh, PA. 1998
    • Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Zakrzewski, V. G.; Montgomery, J. A., Jr.; Stratmann, R. E.; Burant, J. C.; Dapprich, S.; Millam, J. M.; Daniels, A. D.; Kudin, K. N.; Strain, M. C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G. A.; Ayala, P. Y.; Cui, Q.; Morokuma, K.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Cioslowski, J.; Ortiz, J. V.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R. L.; Fox, D. J.: Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.: Andres, J. L.; Gonzalez, C.; Head-Gordon, M.; Replogle, E. S.; Pople, J. A. Gaussian 98, Revision A.6; Gaussian Inc.: Pittsburgh, PA. 1998.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.