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Volumn 111, Issue 25, 2007, Pages 8942-8947

Photovoltage and photocatalyzed growth in citrate-stabilized colloidal silver nanocrystals

Author keywords

[No Author keywords available]

Indexed keywords

COLLOIDAL SILVER NANOCRYSTALS; PHOTOCATALYZED GROWTH; PHOTOCATALYZED REDUCTION; PHOTOVOLTAGE;

EID: 34547358683     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp0710436     Document Type: Article
Times cited : (134)

References (48)
  • 41
    • 0034300983 scopus 로고    scopus 로고
    • Estimated from equation 3 of: Lui, H.; Penner, R. M. J. Phys. Chem. B 2000, 104, 9131.
    • Estimated from equation 3 of: Lui, H.; Penner, R. M. J. Phys. Chem. B 2000, 104, 9131.
  • 43
    • 34547328931 scopus 로고    scopus 로고
    • In molecules, the absorption cross section is orders of magnitude larger than the scattering cross section. Quantum yields from thermally equilibrated excited states are based upon the absorption cross section. In 25 nm Ag particles, the scattering cross section is larger. Even if the absorption cross section were strictly zero, it would be possible for the Ag photo-oxidation reaction to occur in the coherent plasmon state. The quantum yield we quote is the ratio of the oxidation reaction rate to the scattering and absorption rates. The fundamental theoretical question of quantum yield in the presence of both absorption and scattering needs to be considered.
    • In molecules, the absorption cross section is orders of magnitude larger than the scattering cross section. Quantum yields from thermally equilibrated excited states are based upon the absorption cross section. In 25 nm Ag particles, the scattering cross section is larger. Even if the absorption cross section were strictly zero, it would be possible for the Ag photo-oxidation reaction to occur in the coherent plasmon state. The quantum yield we quote is the ratio of the oxidation reaction rate to the scattering and absorption rates. The fundamental theoretical question of quantum yield in the presence of both absorption and scattering needs to be considered.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.