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In molecules, the absorption cross section is orders of magnitude larger than the scattering cross section. Quantum yields from thermally equilibrated excited states are based upon the absorption cross section. In 25 nm Ag particles, the scattering cross section is larger. Even if the absorption cross section were strictly zero, it would be possible for the Ag photo-oxidation reaction to occur in the coherent plasmon state. The quantum yield we quote is the ratio of the oxidation reaction rate to the scattering and absorption rates. The fundamental theoretical question of quantum yield in the presence of both absorption and scattering needs to be considered.
-
In molecules, the absorption cross section is orders of magnitude larger than the scattering cross section. Quantum yields from thermally equilibrated excited states are based upon the absorption cross section. In 25 nm Ag particles, the scattering cross section is larger. Even if the absorption cross section were strictly zero, it would be possible for the Ag photo-oxidation reaction to occur in the coherent plasmon state. The quantum yield we quote is the ratio of the oxidation reaction rate to the scattering and absorption rates. The fundamental theoretical question of quantum yield in the presence of both absorption and scattering needs to be considered.
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