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Angewandte Chemie - International Edition

Volumn 46, Issue 28, 2007, Pages 5384-5388

How to predict the physical properties of ionic liquids: A volume-based approach

(5) Slattery, John M a Daguenet, Corinne b Dyson, Paul J b Schubert, Thomas J S c Krossing, Ingo a

a UNIVERSITY OF FREIBURG (Germany)

b EPFL (Switzerland)

c LoLiTec (Germany)

Author keywords

Ionic liquids; Molecular volumes; Physical properties; Predictive methods; Sustainable chemistry

Indexed keywords

ANION-DEPENDENT EMPIRICAL RELATIONSHIP; MOLECULAR VOLUMES; PREDICTIVE METHODS; SUSTAINABLE CHEMISTRY;

IONIC CONDUCTIVITY; MOLECULAR INTERACTIONS; NEGATIVE IONS; PHYSICAL PROPERTIES; VISCOSITY;

IONIC LIQUIDS;

IONIC LIQUID;

ARTICLE; CHEMISTRY; VISCOSITY;

IONIC LIQUIDS; VISCOSITY;

EID: 34447569404 PISSN: 14337851 EISSN: None Source Type: Journal
DOI: 10.1002/anie.200700941 Document Type: Article

Times cited : (231)

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- It has long been known that the observed physical properties of ILs are strongly affected by the purity of the material.[20] All ILs in this study were synthesized in our laboratories and purified to minimize halide and water content, which were determined by ion chromatography and Karl Fischer titration, respectively (see the Supporting Information for experimental details and physical data, For some ILs physical data were available from both the Dyson laboratory (at the EPFL) and the IoLiTec laboratory in Freiburg. These independent data agree very well and lend confidence to our conclusions. Physical data from the literature were not included in this study, as in many cases an IL is reported to have very different physical properties in two or more studies. The recent founding of an online database for the physical properties of ILs by the National Institute of Standards and Technology (NIST) is very interesting in the context of the work herein.[20e] As the n
- [20e] As the number of ILs in the database increases it should be possible for users to derive similar correlations, for example, involving anions not included in our study, using the data in this database. Nevertheless, care should be taken only to use physical data from very pure ILs (purity information is included in the database) when deriving these correlations.

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- The conductivity correlations do not include nitrile-functionalized ILs, as no experimental conductivity data were available
- The conductivity correlations do not include nitrile-functionalized ILs, as no experimental conductivity data were available.

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- - ILs have a higher content of chloride ions ((180 ± 10) ppm, determined by ion chromatography) than the other ILs in this study (due to chloride impurities in the commercial potassium dicyanamide starting material), which will effect the conductivity measurements.
- - ILs have a higher content of chloride ions ((180 ± 10) ppm, determined by ion chromatography) than the other ILs in this study (due to chloride impurities in the commercial potassium dicyanamide starting material), which will effect the conductivity measurements.

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