Heterogenized gold(I), gold(III), and palladium(II) complexes for C-C bond reactions

Synlett

Volumn , Issue 11, 2007, Pages 1771-1774

  Corma, Avelino ^a   González Arellano, Camino ^b,c   Iglesias, Marta ^b   Pérez Ferreras, Susana ^b,c   Sánchez, Félix ^c  

^a INSTITUTO DE TECNOLOGÍA QUÍMICA   (Spain)

^b INSTITUTO DE CIENCIA DE MATERIALES DE MADRID   (Spain)

^c INSTITUTO DE QUÍMICA ORGÁNICA GENERAL   (Spain)

Author keywords

C C coupling; Gold; Heterogenized; Homogeneous catalysis; Sonogashira; Suzuki

Indexed keywords

ALKYNE; AROMATIC NITRO COMPOUND; BORONIC ACID DERIVATIVE; CARBENE; GOLD COMPLEX; IODOBENZENE; NANOPARTICLE; PALLADIUM COMPLEX; SILICA GEL; TOLUENE;

ARTICLE; ATOMIC ABSORPTION; CATALYSIS; CHEMICAL BOND; COMPLEX FORMATION; CROSS COUPLING REACTION; ENZYME IMMOBILIZATION; MICROANALYSIS; NUCLEAR MAGNETIC RESONANCE; OXIDATION; SONOGASHIRA REACTION; SUZUKI REACTION; SYNTHESIS;

EID: 34447544562     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-984500     Document Type: Article

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34. 4, and filtered. The solvent and volatiles were completely removed under vacuum to give the crude product which subjected to column chromatographic separation resulted in pure compounds. The reaction was followed by GC-MS. At the end of the process, the mixture of reaction was filtered; the residue of support-containing catalyst washed to completely remove the remains of products and/or reactants and used again.
35. 4 (20 mmol) and catalyst (10-20 mol%) in 3 mL of o-xylene was stirred for the desired time. The reaction was followed by GC-MS. At the end of the process, the mixture of reaction was filtered; the residue of support-containing catalyst washed to completely remove the remains of products and/or reactants, and used again.