Hydroxyl radical electrochemically generated with water as the complete atom source and its environmental application

Chinese Science Bulletin

Volumn 52, Issue 10, 2007, Pages 1432-1435

  Cong, Yanqing ^a   Wu, Zucheng ^a   Li, Yuqiong ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Disinfection; Electrochemical process; ESR; Hydroxyl radical; Water purification

Indexed keywords

BACTERIA (MICROORGANISMS);

EID: 34347248053     PISSN: 10016538     EISSN: 18619541     Source Type: Journal    
DOI: 10.1007/s11434-007-0199-8     Document Type: Article

References (18)

1. Meunier B. Chemistry: Catalytic degradation of chlorinated phenols. Science, 2002, 296: 270-271
2. Vione D, Maurino V, Minero C, et al. New processes in the environmental chemistry of nitrite. 2. The role of hydrogen peroxide. Environ Sci Technol, 2003, 37: 4635-4641
3. Theruvathu J A, Aravindakumar C T, Flyunt, R, et al. Fenton chemistry of 1,3-dimethyluracil. J Am Chem Soc, 2001, 123: 9007-9014
4. Buxton G V, Greenstock C L, Helman W P, et al. Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous solution, J Phys Chem Ref Data, 1988, 17: 513-886
5. Bach R D, Dmitrenko O. The "somersault" mechanism for the P-450 hydroxylation of hydrocarbons, the intervention of transient inverted metastable hydroperoxides. J Am Chem Soc, 2006, 128: 1474-1488
6. Perez-Estrada L A, Malato S, Gemjak W, et al. Photo-fenton degradation of diclofenac: identification of main intermediates and degradation pathway. Environ Sci Technol, 2005, 39: 8300-8306
7. Bohne C, Faulhaber K, Giese B, et al. Studies on the mechanism of the photo-induced DNA damage in the presence of acridizinium salts-involvement of singlet oxygen and an unusual source for hydroxyl radicals. J Am Chem Soc, 2005, 127: 76-85
8. Sallustio B C, DeGraaf Y C, Weekley J S, et al. Bioactivation of carboxylic acid compounds by UDP-glucuronosyltransferases to DNA-damaging intermediates: Role of glycoxidation and oxidative stress in genotoxicity. Chem Res Toxicol, 2006, 19: 683-691
9. Southworth B A, Voelker B M. Hydroxyl radical production via the photo-fenton reaction in the presence of fulvic acid. Environ Sci Technol, 2003, 37: 1130-1136
10. Fang H J, Ouyang B, Qin Y, et al. Study on the reaction of carbon disulfide with hydroxyl radical in aqueous solution, Chin Sci Bull, 2005, 50: 2832-2835
11. Foley S, Rotureau P, Pin S, et al. Radiolysis of confined water: Production and reactivity of hydroxyl radicals. Angew Chem Int Ed, 2005, 44: 110-112
12. Poole J S, Shi X, Hadad C M, et al. Reaction of hydroxyl radical with aromatic hydrocarbons in nonaqueous solutions: A laser flash photolysis study in acetonitrile. J Phys Chem A, 2005, 109: 2547-2551
13. Sorokin A, SJris J L, Meunier B. Efficient oxidative dechlorination and aromatic ring cleavage of chlorinated phenols catalyzed by iron sulfophthalocyanine. Science, 1995,268: 1163-1166
14. Wu Z C, Zhou M H. Partial degradation of phenol by advanced electrochemical oxidation process. Environ Sci Technol, 2001, 35: 2698-2703
15. Wu Z C, Cong Y Q, Zhou M H, et al. p-Nitrophenol abatement by the combination of electrocatalysis and activated carbon. Chem Eng J, 2005, 106: 83-90
16. Wu Z C, Cong Y Q, Zhou M H, et al. Removal of phenolic compounds by electro-assisted advanced process for wastewater purification. Korean J Chem Eng, 2002, 19: 866-870
17. Blatchley III E R, Margetas D, Duggirala R. Copper catalysis in chloroform formation duringwater chlorination. Water Res, 2003, 37: 4385-4394
18. Environmental Protection Agency. Disinfectants, disinfection by-products, final rule-National Primary Drinking Water Regulations. Federal Register, 1998, 63: 69390-69476