Highly diastereoselective synthesis of β-carboxy-γ-lactams and their ethyl esters via Sc(OTf)3-catalyzed imino Mukaiyama-aldol type reaction of 2,5-bis(trimethylsilyloxy)furan with imines

Journal of Organic Chemistry

Volumn 72, Issue 13, 2007, Pages 5016-5019

  Pohmakotr, Manat ^a   Yotapan, Nattawut ^a   Tuchinda, Patoomratana ^a   Kuhakarn, Chutima ^a   Reutrakul, Vichai ^a  

^a MAHIDOL UNIVERSITY   (Thailand)

Author keywords

[No Author keywords available]

Indexed keywords

DIASTEREOMERIC RATIO; ETHYL ESTERS; IMINES;

CATALYSTS; DERIVATIVES; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ESTERS;

1 BENZYL 5 OXO 2 PHENYLPYRROLIDINE 3 CARBOXYLIC ACID; 2,5 BIS(TRIMETHYLSILYLOXY)FURAN; ESTER DERIVATIVE; ETHYL 5 OXO 1,2 DIPHENYLPYRROLIDINE 3 CARBOXYLIC ACID; GAMMA LACTAM DERIVATIVE; IMINE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTALLIZATION; DIASTEREOISOMER; ISOMERISM; MUKAIYAMA REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE; STEREOCHEMISTRY;

CARBOXYLIC ACIDS; CATALYSIS; ESTERS; ETHYLENES; FURANS; IMINES; LACTAMS; MESYLATES; MOLECULAR STRUCTURE; SCANDIUM; STEREOISOMERISM; TRIMETHYLSILYL COMPOUNDS;

EID: 34250885710     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo070533r     Document Type: Article

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