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Crystal data for 1: crystal dimensions 0.13 x 0.11 x 0.02 mm, C32H33BN, Mr, 442.40, monoclinic, space group P21/n, a, 15.979(3, b, 9.0599(18, c, 18.109(4) Å, β, 104.34(3)°, V, 2540.0(9) Å3, Z, 4, ρcalcd, 1.157 g cm -3, CuKα radiation (λ, 1.54178 Å, T, 110(2) K, 17 755 measured reflections, 3573 unique, R int, 0.0793, R1, 0.0985, wR2, 0.1819 (all data, The crystal was mounted onto a nylon loop with Apiezon grease. The structure was solved by direct methods, which successfully located most of the non-hydrogen atoms. Subsequent refinement on F2 with the SHELXTL/PC package (version 5.1) allowed location of the remaining non-hydrogen atoms. CCDC-623112 contains the supplementary crystallographic data for this pa
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2 with the SHELXTL/PC package (version 5.1) allowed location of the remaining non-hydrogen atoms. CCDC-623112 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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