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Similar types of σ dimers, and occasionally π dimers, have been reported for related compounds, such as tetracyanoethylene (TCNE) derivatives: J. S. Miller, Angew. Chem. 2006, 118, 2570;
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b) Similar types of σ dimers, and occasionally π dimers, have been reported for related compounds, such as tetracyanoethylene (TCNE) derivatives: J. S. Miller, Angew. Chem. 2006, 118, 2570;
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34250815448
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39
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34250888504
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-
In all scans, nitrobenzene shows a one-electron reversible reduction wave, and dinitrobenzene two successive one-electron reversible reduction waves
-
In all scans, nitrobenzene shows a one-electron reversible reduction wave, and dinitrobenzene two successive one-electron reversible reduction waves.
-
-
-
-
40
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34250844161
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Electrochemical Reactions in Investigation of Rates and Mechanism of Reactions: C. P. Andrieux, J.-M. Savéant in Techniques of Chemistry, 6 (Ed.: C. F. Bernasconi), Wiley, New York, 1986, chap. 2.1.
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"Electrochemical Reactions in Investigation of Rates and Mechanism of Reactions": C. P. Andrieux, J.-M. Savéant in Techniques of Chemistry, Vol. 6 (Ed.: C. F. Bernasconi), Wiley, New York, 1986, chap. 2.1.
-
-
-
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42
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34250806918
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Simulations were performed by using DIGISIM software, which is commercially available from BAS Corp
-
Simulations were performed by using DIGISIM software, which is commercially available from BAS Corp.
-
-
-
-
43
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34250791930
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-
[13b]
-
[13b]
-
-
-
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44
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4544271316
-
-
Investigations by Taylor and Farnham under different environmental conditions showed that the fluorescence quantum yields of o complexes are about 0.09 S. Farnham, R. Taylor, J. Org. Chem. 1974, 39, 2446
-
b) Investigations by Taylor and Farnham under different environmental conditions showed that the fluorescence quantum yields of o complexes are about 0.09 (S. Farnham, R. Taylor, J. Org. Chem. 1974, 39, 2446).
-
-
-
-
45
-
-
0035901650
-
-
Recent results have shown that the oxidation potential of σ complexes are in the range of 0.60-1.00 V: a I. Gallardo, G. Guirado, J. Marquet, Chem. Eur. J. 2001, 7, 1759;
-
Recent results have shown that the oxidation potential of σ complexes are in the range of 0.60-1.00 V: a) I. Gallardo, G. Guirado, J. Marquet, Chem. Eur. J. 2001, 7, 1759;
-
-
-
-
46
-
-
34250856613
-
-
I. Gallardo, G. Guirado, J. Marquet, ES2179727, 2003;
-
b) I. Gallardo, G. Guirado, J. Marquet, ES2179727, 2003;
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49
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0037134215
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e) I. Gallardo, G. Guirado, J. Marquet, J. Org. Chem 2002, 67, 2548.
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J. Org. Chem
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Gallardo, I.1
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52
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34250823283
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[4a,8] b The maximum absorption of 2 was determined in our laboratory.
-
[4a,8] b) The maximum absorption of 2 was determined in our laboratory.
-
-
-
-
53
-
-
34250825719
-
-
12): N 16.37, C 48.98, H 6.71; found: N 15.94, C 48.60, H 6.72.
-
12): N 16.37, C 48.98, H 6.71; found: N 15.94, C 48.60, H 6.72.
-
-
-
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54
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34250878775
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Crystal structure analysis of (Et4N)2-2 (C14H23N4O6, Mr, 343.36 g mol-1, A green needle was rapidly mounted under Paratone-8277 on a glass fiber and immediately placed in a cold nitrogen stream at -80°C on a Bruker diffractometer with SMART CCD area detector. Crystal size 0.28 x 0.05 x 0.03 mm; monoclinic, space group P21/c; a, 11.657(2, b, 6.7546(14, c, 23.262(4) Å, β, 115.988(7)°, V, 1646.4(5) Å3, Z, 4; ρcalcd, 1.671 g cm-3; μ, 0.109 mm-1; 2θmax, 56.6°, λ(MoKα, 0.71073 Å. 9295 reflections collected (1535 unique reflections, R int, 0.1131, Data were corrected for absorption with the SADABS[18b] program. The structure was solved by direct methods and refined 218
-
-3. CCDC-616742 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif;
-
-
-
-
55
-
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84977289324
-
-
The SADABS program is based on the Blessing method: R. H. Blessing, Acta Crystallogr. Sect. A 1995, 51, 33;
-
b) The SADABS program is based on the Blessing method: R. H. Blessing, Acta Crystallogr. Sect. A 1995, 51, 33;
-
-
-
-
56
-
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34250793115
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SHELXTL NT: Structure Analysis Program, version 5.10, Bruker-AXS, Madison, WI, 1995
-
c) SHELXTL NT: Structure Analysis Program, version 5.10, Bruker-AXS, Madison, WI, 1995.
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57
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0003431029
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Wiley, New York
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36749115173
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to our knowledge, only one solid biradical has been obtained by photolysis: c K. Mukai, T. Tamaki, J. Chem. Phys. 1978, 68, 2006.
-
b) to our knowledge, only one solid biradical has been obtained by photolysis: c) K. Mukai, T. Tamaki, J. Chem. Phys. 1978, 68, 2006.
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4243691103
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8344235420
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33751516165
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f) D. Collison, M. Helliwell, V. M. Jones, F. E. Mabbs, E. J. L. Mc Innes, P. C. Riedi, G. M. Smith, R. G. Pritchasrd, W. I. Cross, J. Chem. Soc. Faraday Trans. 1998, 94, 3019;
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65
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0001580360
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0343773057
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a) M. A. Muñoz, O. Sama, M. Galán, P. Guardado, C. Carmona, M. Balón, Spectrochim. Acta Part A 2001, 57, 1049;
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Muñoz, M.A.1
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67
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34250837235
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3CN was determined in relation to the fluorescence quantum yield of N′, N″,N‴-triisopropyl-4-oxo-6-isopropyliminio-2s- (2H)-triazinespiro-1′,2′,4′,6′- trinitrocyclohexadienylide (0.5);
-
3CN was determined in relation to the fluorescence quantum yield of N′, N″,N‴-triisopropyl-4-oxo-6-isopropyliminio-2s- (2H)-triazinespiro-1′,2′,4′,6′- trinitrocyclohexadienylide (0.5);
-
-
-
-
68
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4544338172
-
-
3CN, a compound with similar features: R. O. Al-Kaysi, G. Guirado, E. J. Valente, Eur. J. Org. Chem. 2004, 3408.
-
3CN, a compound with similar features: R. O. Al-Kaysi, G. Guirado, E. J. Valente, Eur. J. Org. Chem. 2004, 3408.
-
-
-
-
69
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34250834150
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Crystal structure analysis for (Et4N)2-4 (C28H46N10O12, Mr, 714.75 g mol-1) was perfomed on a Nonius Kappa CCD diffractometer. Crystal size 0.16 x 0.07 x 0.05 mm; monoclinic, space group P2 1/c; a, 13.131(5, b, 19.359(5, c, 13.926(5) Å, β, 104.043(5)°, V, 3434(2) Å3, Z, 4; ρcalcd, 1.382 g cm-3; μ, 0.109 mm-1; 2θ, 54.7°; λ(MoKα, 0.71073 Å, T, 293(2) K. 42 967 reflections collected (7606 unique reflections, Rint, 0.1286, The structure was solved by direct methods and refined (452 parameters) by full-matrix least-squares methods on F2 with the SHELXTL package.[18c] Hydrogen atoms were calculated and placed in idealized positions. The structure was refined t
-
-3). CCDC-195183 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/datarequest/cif.
-
-
-
-
70
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34250825083
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[2i, 23b] Since 2 evolves spontaneously into 3, the system can be considered a dynamic switch combining chromic and magnetic outputs;
-
[2i, 23b] Since 2 evolves spontaneously into 3, the system can be considered a dynamic switch combining chromic and magnetic outputs;
-
-
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71
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0001203383
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b) R. Rathore, P. Le Magueres, S. V. Lindeman, J. K. Kochi, Angew. Chem. 2000, 112, 818;
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Angew. Chem
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Rathore, R.1
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Kochi, J.K.4
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