Single crystal of a prussian blue analog based on rubidium manganese hexacyanoferrate

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 633, Issue 8, 2007, Pages 1134-1136

  Tokoro, Hiroko ^a   Shiro, Motoo ^b   Hashimoto, Kazuhito ^a   Ohkoshi, Shin Ichi ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b RIGAKU CORPORATION   (Japan)

Author keywords

Crystal structure; Cyanide bridged metal complexes; Prussian blue analog

Indexed keywords

EID: 34250816943     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200700129     Document Type: Article

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24. The magnetic susceptibility vs. temperature plots indicate that the present single crystal does not show the charge transfer phase transition although the powder-form samples with x > 0.61 show the phase transition in our previous reports [20]. Maybe, this is because the size of the present single crystal is large (∼ 100 μm). The detailed study for the relationship bwtween the charge transfer phase transition and the crystal size is now under investigation.
25. Further details are available from the Fachinformationszentrum (FIZ) Karlsruhe, D-76344 Eggenstein-Leopoldshafen (crysdata@fiz-karlsruhe.de) by quoting the depository number CSD 417499.