Homologation of propane catalyzed by oxide-supported zirconium dihydride and dialkyl complexes

Angewandte Chemie - International Edition

Volumn 46, Issue 13, 2007, Pages 2288-2290

  Thieuleux, Chloé ^a   Maraval, Alexandrine ^a   Veyre, Laurent ^a   Copéret, Christophe ^a   Soulivong, Daravong ^a   Basset, Jean Marie ^a   Sunley, Glenn J ^b  

^a UMR 5265   (France)

^b BP EXPLORATION   (United Kingdom)

Author keywords

Alkanes; C C coupling; Heterogeneous catalysis; Hydrides; Zirconium

Indexed keywords

CATALYSIS; CATALYSTS; COMPLEXATION; HYDRIDES; POLYMERIZATION; SILICA; ZIRCONIUM COMPOUNDS;

DIALKYL COMPLEXES; HOMOLOGATION; ZIRCONIUM DIHYDRIDE;

PROPANE;

EID: 34250791585     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200604158     Document Type: Article

References (32)

1. V. A. Zakharov, V. K. Dudchenko, A. M. Kolchin, Y. I. Ermakov, Kinet. Katal. 1975, 16, 808.
2. V. A. Zakharov, Y. A. Ryndin, J. Mol. Catal. 1989, 56, 183.
3. J. Schwartz, M. D. Ward, J. Mol. Catal. 1980, 8, 465.
4. S. A. King, J. Schwartz, Inorg. Chem. 1991, 30, 3771.
5. R. D. Profilet, A. P. Rothwell, I. P. Rothwell, J. Chem. Soc. Chem. Commun. 1993, 42.
6. C. Lécuyer, F. Quignard, A. Choplin, D. Olivier, J. M. Basset, Angew. Chem. 1991, 103, 1692;
7. Angew. Chem. Int. Ed. Engl. 1991, 30, 1660.
8. J. Corker, F. Lefebvre, C. Lecuyer, V. Dufaud, F. Quignard, A. Choplin, J. Evans, J.-M. Basset, Science 1996, 271, 966.
9. V. Dufaud, J.-M. Basset, Angew. Chem. 1998, 110, 848;
10. Angew. Chem. Int. Ed. 1998, 37, 806.
11. C. Thieuleux, C. Copéret, V. Dufaud, C. Marangelli, E. Kuntz, J. M. Basset, J. Mol. Catal. A 2004, 213, 47.
12. M. Chabanas, V. Vidal, C. Copéret, J. Thivolle-Cazat, J.-M. Basset, Angew. Chem. 2000, 112, 2038;
13. Angew. Chem. Int. Ed. 2000, 39, 1962.
14. J. J. Mortensen, M. Parrinello, J. Phys Chem. B 2000, 104, 2901.
15. M. N. Mikhailov, L. M. Kustov, Russ. Chem. Bull. 2005, 54, 300.
16. V. Vidal, A. Theolier, J. Thivolle-Cazat, J.-M. Basset, Science 1997, 276, 99.
17. E. Le Roux, M. Chabanas, A. Baudouin, A. de Mallmann, C. Copéret, E. A. Quadrelli, J. Thivolle-Cazat, J.-M. Basset, W. Lukens, A. Lesage, L. Emsley, G. J. Sunley, J. Am. Chem. Soc. 2004, 126, 13391.
18. J. M. Basset, C. Copéret, L. Lefort, B. M. Maunders, O. Maury, E. Le Roux, G. Saggio, S. Soignier, D. Soulivong, G. J. Sunley, M. Taoufik, J. Thivolle-Cazat, J. Am. Chem. Soc. 2005, 127, 8604.
19. F. Quignard, A. Choplin, J. M. Basset, J. Chem. Soc. Chem. Commun. 1991, 1589.
20. C. Thieuleux, E. A. Quadrelli, J.-M. Basset, J. Doebler, J. Sauer, Chem. Commun. 2004, 1729.
21. E. Le Roux, M. Taoufik, C. Copéret, A. de Mallmann, J. Thivolle-Cazat, J.-M. Basset, B. M. Maunders, G. J. Sunley, Angew. Chem. 2005, 117, 6913;
22. Angew. Chem. Int. Ed. 2005, 44, 6755.
23. C. Copéret, O. Maury, J. Thivolle-Cazat, J.-M. Basset, Angew. Chem. 2001, 113, 2393;
24. Angew. Chem. Int. Ed. 2001, 40, 2331.
25. J. L. Hérisson, Y. Chauvin, Makromol. Chem. 1971, 141, 161.
26. L. Y. Ustynyuk, Y. A. Ustynyuk, D. N. Laikov, V. V. Lunin, Russ. Chem. Bull. 2001, 50, 2050.
27. C. Copéret, A. Grouiller, M. Basset, H. Chermette, ChemPhysChem 2003, 4, 608.
28. L. Resconi, L. Cavallo, A. Fait, F. Piemontesi, Chem. Rev. 2000, 100, 1253.
29. F. Rataboul, A. Baudouin, C. Thieuleux, L. Veyre, C. Copéret, J. Thivolle-Cazat, J.-M. Basset, A. Lesage, L. Emsley, J. Am. Chem. Soc. 2004, 126, 12541.
30. Isobutene could also be formed by a methyl transfer from the propyl chain directly into propene as proposed by Baird and Yang: P. Yang, M. C. Baird, Organometallics 2005, 24, 6005.
31. X.-X. Wang, L. Veyre, F. Lefebvre, J. Patarin, J.-M. Basset, Microporous Mesoporous Mater. 2003, 66, 169.
32. 2] (R = rBu), while the silicaalumina- or silica-supported zirconium hydride contains only 30% of dihydride species, hence the difference in intrinsic inverse space velocity (number of active sites/flow rate), and thereby final product selectivities.