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Volumn , Issue 9, 2007, Pages 1215-1218

A two-dimensional, hydrogen-bond-cross-linked molybdenum(VI) network polymer with catalytic activity

Author keywords

Crystal engineering; Epoxidation; Hydrogen bonds; Hydrogen peroxide; Molybdenum

Indexed keywords

CROSSLINKING; HYDROGEN BONDS; MOLYBDENUM COMPOUNDS; SODIUM BICARBONATE;

EID: 34250781052     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200601054     Document Type: Article
Times cited : (18)

References (25)
  • 18
    • 85163239992 scopus 로고    scopus 로고
    • Experimental details: MoO3 (0.826 g, 5.74 mmol) was dissolved in excess concentrated HCl by stirring at 40°C for 4 h; a pale yellow solution was obtained. The solution was cooled in an ice bath, and a solution of a dipy-pra (1.138 g, 5.74 mmol) in ethanol (10 mL) was then added in portions. After stirring for 6 h, a yellow solution was obtained, which when left overnight at ca. 4°C afforded the lemon yellow crystalline complex 1 in 1.48 g, 51% yield. The characterization results are as follows: C13H 20Cl4MoN2O4 (506.66, calcd. C 30.85, H 3.98, Mo 18.96, N 5.54, O22- 12.65; found C 30.71, H 4.11, Mo 18.91, N 5.46, O22- 12.87. IR (KBr disc; selected bands, 952, 936 (MoO2, asym, 906 MoO2, sym, cm-1. Crystal data for 1 at 293 K: C13H 20N2O4Cl4Mo, M, 506.05, triclinic, space
    • -1, F(000) = 508, 10144 reflections measured, 4632 unique. CCDC-614792 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.