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Diffraction data for 1 were collected at 150 K on a Bruker Smart Apex CCD diffractometer equipped with an Oxford Cryosystems low-temperature device. The structure was solved by direct methods (SHELXS) and refined by full-matrix least squares against F2 (CRYSTALS, CCDC-639301 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via 1·8C 6H14: C88H212Mn10N 10O24Br7, Mr, 2599.81 g mol-1, T, 150 K, rhombohedral, space group R3, a, 15.6083(4, c, 76.462(5) Å, V, 16132.0(1) Å3, dcalcd, 1.606 gem-3, independent reflections 7364 [Rint, 0.066, data 7364, parameters 261, wR2, 0
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2 1.051, final R1 = 0.0464 for 5522 reflections with F > 4σ(F).
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24
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33745655195
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For a recent review, see:, and references therein
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26
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34250761161
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The low-temperature and high-field experimental range turns out to be particularly relevant to determine the lattice contribution arising from acoustic low-energy phonons (Debye model, The fit provides the Debye temperature θD, 30.6 K dotted line in Figure 3 a
-
D = 30.6 K (dotted line in Figure 3 a).
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27
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33748608843
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