Mixed-valent cobalt spin clusters: A hexanuclear complex and a one-dimensional coordination polymer comprised of alternating hepta- and mononuclear fragments

Inorganic Chemistry

Volumn 45, Issue 22, 2006, Pages 8950-8957

  Alley, Kerwyn G ^a   Bircher, Roland ^b   Waldmann, Oliver ^b   Ochsenbein, Stefan T ^b   Gudel, Hans U ^b   Moubaraki, Boujemaa ^c   Murray, Keith S ^c   Fernandez Alonso, Felix ^d   Abrahams, Brendan F ^a   Boskovic, Colette ^a  

^a UNIVERSITY OF MELBOURNE   (Australia)

^b UNIVERSITY OF BERN   (Switzerland)

^c MONASH UNIVERSITY   (Australia)

^d RUTHERFORD APPLETON LABORATORY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33751420994     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060938e     Document Type: Article

References (52)

1. Gatteschi, D.; Sessoli, R. Angew. Chem., Int. Ed. 2003, 42, 268 and references cited therein.
2. (a) Holmes, S. D.; Girolami, G. S. J. Am. Chem. Soc. 1999, 121, 5593.
3. (b) Hatlevik, Ø.; Buschmann, W. E.; Zhnag, J.; Manson, J. L.; Miller, J. S. Adv. Mater. 1999, 11, 914.
4. (c) Verdaguer, M.; Girolami, G. S. In Magnetism: Molecules to Materials V; Miller, J. S., Drillon, M., Eds.; Wiley-VCH: Weinheim, Germany, 2005; p 347.
5. (a) Robson, R. Dalton Trans. 2000, 3735.
6. (b) Janiak, C. Dalton Trans. 2003, 2781.
7. (c) James, S. L. Chem. Soc. Rev. 2003, 32, 276.
8. Eddaoudi, M.; Moler, D. B.; Li. H.; Chen, B.; Reineke, T. M.; O'Keefe, M.; Yaghi, O. M. Acc. Chem. Res. 2001, 34, 319 and references cited therein.
9. Ferbinteanu, M.; Miyasaka, H.; Wernsdorfer, W.; Nakata, K.; Sugira, K.; Yamashita-, M.; Coulon, C.; Clerac, R. J. Am. Chem. Soc. 2005, 127, 3090 and references cited therein.
10. (a) Caneschi, A.; Gatteschi, D.; Lalioti, N.; Sangregorio, C.; Sessoli, R.; Venturi, G.; Vindigni, A.; Rettori, A.; Pini, M. G.; Novak, M. A. Angew. Chem., Int. Ed. 2001, 40, 1760.
11. (b) Lescouezec, R.; Vaissermann, J.; Ruiz-Perez, C.; Lloret, F.; Carrasco, R.; Julve, M.; Verdaguer, M.; Dromzee, Y.; Gatteschi, D.; Wernsdorfer, W. Angew. Chem., Int. Ed. 2003, 42, 1483.
12. (c) Liu, T. F.; Fu, D.; Gao, S.; Zhang, Y. Z.; Sun, H. L.; Su, G.; Liu, Y. J. J. Am. Chem. Soc. 2003, 125, 13976.
13. (d) Pardo, E.; Lloret, F.; Faus, J.; Julve, M.; Journaux, Y.; Delgado, F.; Ruiz-Perez, C. Adv. Mater. 2004, 16, 1597.
14. (e) Ishii, N.; Ishida, T.; Mogami, T. Inorg. Chem. 2006, 45, 3837.
15. Chakov, N. E.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Inorg. Chem. 2004, 43, 5919.
16. Labat, G.; Boskovic, C.; Güdel, H. U. Acta Crystallogr. 2005, E61, m611.
17. Alley, K. G.; Bircher, R.; Güdel, H. U.; Moubaraki, B.; Murray, K. S.; Abrahams, B. F.; Boskovic, C. Polyhedron 2006, doi:10.1016/j.poly.2006.06. 028.
18. McKee, V.; Wilkins, C. J. J. Chem. Soc., Dalton Trans. 1987, 523.
19. Laye, R. H.; McInnes, E. J. L Eur. J. Inorg. Chem. 2004, 14, 2811.
20. Sheldrick, G. M. SHELX97 Programs for Crystal Structure Analysis; Universitat Göttingen: Göttingen, Germany, 1998.
21. Adams, M. A.; Howells, W. S.; Telling, M. T. F. Technical Report RAL-TR-2001-002; Rutherford Appleton Laboratory: Oxfordshire, U.K., 2001.
22. (a) Christou, G. C. Acc. Chem. Res. 1989, 22, 328.
23. (b) Winpenny, R. E. P. Adv. Inorg. Chem. 2001, 52, 1.
24. (c) Brechin, E. K. Chem. Commun. 2005, 41, 5141.
25. Brese, N. E.; O'Keefe, M. Acta Crystallogr. 1991, B47, 192.
26. (a) Xia, X.; Verelst, M.; Daran, J.-C; Tuchagues, J.-P. Chem. Commun. 1995, 2155.
27. (b) Rajamaran, G.; Murugesu, M.; Sanudo, E. C.; Soler, M.; Wernsdorfer, W.; Helliwell, M.; Muryn, C.; Raftery, J.; Teat, S. J.; Christou, G. C.; Brechin, E. K. J. Am. Chem. Soc. 2004, 126, 15445.
28. (a) Bolcar, M. A.; Aubin, S. M. J.; Folting, K.; Hendrickson, D. N.; Christou, G. Chem. Commun. 1997, 1485.
29. (b) Abbati, G. L.; Cornia, A.; Fabretti, A. C.; Caneschi, A.; Gatteschi, D. Inorg. Chem. 1998, 37, 3759.
30. (c) Oshio, H.; Hoshino, N.; Ito, T.; Nakano, M.; Renz, F.; Gütlich, P. Angew. Chem., Int. Ed. 2003, 42, 223.
31. (a) Chiang, R. K.; Huang, C. C.; Wur, C. S. Inorg. Chem. 2001, 40, 3237.
32. (b) Li, Y. G.; Wang, E. B.; Ling, Y.; Hu, C. W.; Xu, L. Eur. J. Inorg. Chem. 2003, 2567.
33. (c) Zhou, X. G.; Han, Z. G.; Peng, J.; Chen, J. S.; Wang, E. B.; Tian, C. G.; Duan, L. Y.; Hu, N. H. Inorg. Chem. Commun. 2003, 6, 1429.
34. (d) Yuan, D.; Xu, Y.; Hong, M.; Zhou, Y.; Li, Y. Eur. J. Inorg. Chem. 2005, 1182.
35. (e) Jones, L. F.; Jensen, P.; Moubaraki, B.; Cashion, J. D.; Berry, K. J.; Murray, K. S. Dalton Trans. 2005, 3344.
36. (a) Kahn, O. Molecular Magnetism; Wiley-VCH: Weinheim, Germany, 1993; p 38.
37. (b) Boca, R. Struct. Bonding 2006, 117, 1.
38. Mabbs, F. E.; Machin, D. J. Magnetism and Transition Metal Complexes; Chapman and Hall: London, 1973; p 87.
39. Du, M.; Guo, Y. M.; Bu, X. H.; Ribas, J. Eur. J. Inorg. Chem. 2004, 3228.
40. Berry, J. F.; Cotton, F. A.; Liu, C. Y.; Lu, T.; Murillo, C. A.; Tsukerblat, B. S.; Villagran, D. S.; Wang, X. J. Am. Chem. Soc. 2005, 127, 4895.
41. II ions did not provide results significantly better than those obtained with eq 3.
42. Basler, R.; Boskovic, C.; Chaboussant, G.; Güdel, H. U.; Murrie, M.; Ochsenbein, S. T.; Sieber, A. Chem. Phys. Chem. 2003, 4, 910.
43. (a) Clemente-Juan, J. M.; Coronado, E.; Gaita-Arino, A.; Gimenez-Saiz, C.; Güdel, H. U.; Sieber, A.; Bircher, R.; Mutka, H. Inorg. Chem. 2005, 44, 3389.
44. (b) Andres, H.; Clemente-Juan, J. M.; Aebersold, M.; Güdel, H. U.; Coronado, E.; Buettner, H.; Kearly, G.; Melero, J.; Burriel, R. J. Am. Chem. Soc. 1999, 121, 10028.
45. (c) Andres, H.; Clemente-Juan, J. M.; Basler, R.; Aebersold, M.; Güdel, H. U.; Borras-Almenar, J. J.; Gaita, A.; Coronado, E.; Buettner, H.; Janssen, S. Inorg. Chem. 2001, 40, 1943.
46. (d) Clemente-Juan, J. M.; Andres, H.; Borras-Almenar, J. J.; Coronado, E.; Güdel, H. U.; Aebersold, M.; Kearly, G.; Buettner, H.; Zolliker, M. J. Am. Chem. Soc. 1999, 121, 10021.
47. Borras-Almenar, J. J.; Clemente-Juan, J. M.; Coronado, E.; Tsukerblat, B. S. J. Comput. Chem. 2001, 22, 985.
48. Pei, Y.; Nakatani, K.; Kahn, O.; Sletten, J.; Renard, J. P. Inorg. Chem. 1989, 28, 3170 and references cited therein.
49. (a) Yang, E. C.; Hendrickson, D. N.; Wernsdorfer, W.; Nakano, M.; Zakharov, L. N.; Sommer, R. D.; Rheingold, A. L.; Ledezma-Gairaud, M.; Christou, G. J. Appl. Phys. 2002, 91, 7382.
50. (b) Murrie, M.; Teat, S. J.; Stoeckli-Evans, H.; Güdel, H. U. Angew. Chem., Int. Ed. 2003, 42, 4653.
51. (c) Langley, S. J.; Helliwell, M.; Sessoli, R.; Rosa, P.; Wernsdorfer, W.; Winpenny, R. E. P. Chem. Commun. 2005, 5029.
52. (d) Boudalis, A. K.; Raptopolou, C. P.; Abarca, B.; Ballesteros, R.; Chadlaoui, M.; Tuchagues, J. P.; Terzis, A. Angew. Chem, Int. Ed. 2006, 45, 432.